Catalyzed Mizoroki-Heck Reaction or C-H Activation

Berteina‐Raboin, Sabine

doi:10.3390/catal9110925

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Cited by 4 publications

References 10 publications

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Unusual selectivity in gold-catalyzed intermolecular Heck reactions

Thoke,

Patil

2023

Gold Bull

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Unusual selectivity in gold-catalyzed intermolecular Heck reactions

Thoke,

Patil

2023

Gold Bull

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Gold-Catalyzed Heck Reaction

et al. 2023

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Herein, we report a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au(I)/Au(III) redox catalysis. The elementary organometallic steps such as migratory insertion and β-hydride elimination have been realized in the catalytic fashion for the first time in gold chemistry. The present methodology not only overcomes the limitations of previously known transition metalcatalyzed Heck reactions such as the requirement of specialized substrates and formation of a mixture of regioisomeric products as a result of the undesirable chain-walking process but also offers complementary regioselectivity as compared to other transition metal catalysis.

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Heck Reactions

2022

Greener Organic Transformations

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In 1972, Heck and Nolley reported the palladium-catalysed vinylic hydrogen substitution reaction with aryl, benzyl and styryl halides, in the presence of a hindered amine, to yield substituted alkenes, i.e. the Heck reaction. This chapter begins with a discussion of the Heck reaction in the synthesis of various industrially useful molecules. It then considers issues of catalyst separation, discusses direct C–H coupling, catalyst development, photo-induced reactions, use of alternative solvents or solvent-free reactions, microwaves and flow chemistry.

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Catalyzed Mizoroki-Heck Reaction or C-H Activation

Abstract: In the last few decade, research conducted on the development by catalytic processes of C-C bonds formation on the one hand and on the other hand on the activation of C-H bonds has grown considerably [...]

Cited by 4 publications

References 10 publications

Unusual selectivity in gold-catalyzed intermolecular Heck reactions

Unusual selectivity in gold-catalyzed intermolecular Heck reactions

Gold-Catalyzed Heck Reaction

Heck Reactions

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