Catalytic Transformations Based on Iodine(I) Involving Radical Pathways

Bosnidou, Alexandra E.; Romero, R. Martín

doi:10.1002/9783527829569.ch5

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2023

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Cited by 2 publications

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“…Such examples have been reviewed by Muñiz in a book chapter. 21 Some individual examples from our review have been covered in reviews about homolysis 22 and direct photoexcitation strategy. 23…”

Section: Introductionmentioning

confidence: 99%

Transformations based on direct excitation of hypervalent iodine(iii) reagents

Narobe

Koenig

2023

Org. Chem. Front.

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Section: Introductionmentioning

confidence: 99%

Transformations based on direct excitation of hypervalent iodine(iii) reagents

Narobe

Koenig

2023

Org. Chem. Front.

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Iodine(III)‐Mediated Oxidation of Anilines to Construct Dibenzazepines**

White

Zorigt

Deng

et al. 2023

Chemistry A European J

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The development of an efficient process that produces bioactive medium-sized N-heterocyclic scaffolds from 2-substituted anilines using either iodosobenzene or (bis(trifluoroacetoxy)iodo)-benzene is reported. The tether between the sulfonamide and the aryl group can be varied to access dihydroacridine-, dibenzazepine-, or dibenzazocine scaffolds. While substitution on the aniline portion is limited to electron-neutral-or electron-poor groups, a broader range of functional groups are tolerated on the ortho-aryl substituent and site selective CÀ NAr bond formation can be achieved. Preliminary mechanistic investigations suggest that mediumring formation occurs via radical reactive intermediates.

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Catalytic Transformations Based on Iodine(I) Involving Radical Pathways

Cited by 2 publications

References 96 publications

Transformations based on direct excitation of hypervalent iodine(iii) reagents

Transformations based on direct excitation of hypervalent iodine(iii) reagents

Iodine(III)‐Mediated Oxidation of Anilines to Construct Dibenzazepines**

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