Catalytic stereoselective Mannich-type reactions for construction of fluorinated compounds

Dabiri, Minoo; Lehi, Noushin Farajinia; Mohammadian, Reza

doi:10.1007/s11030-021-10235-1

Mol Divers

2021

DOI: 10.1007/s11030-021-10235-1

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Catalytic stereoselective Mannich-type reactions for construction of fluorinated compounds

Minoo Dabiri

Noushin Farajinia Lehi

Reza Mohammadian

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2024

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Functionalized α‐Fluorinated Amines from Imines and Enol Ethers

Kyrko,

Saraç,

Hao

et al. 2024

Adv Synth Catal

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We report the addition reaction of lithium enol ethers to fluoroalkyl imines. A range of different fluoroalkyls and lithiated reagents are well tolerated. Diastereoselective addition of lithium vinyl ethers to fluoroalkyl N‐tert‐butanesulfinylimines is disclosed, providing enantiomerically enriched α‐fluorinated amines up to 98%. This general approach led to the diastereoselective formation of various amino‐alcohols and amino‐ethers, which are difficult to achieve with other methods.

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Functionalized α‐Fluorinated Amines from Imines and Enol Ethers

Kyrko,

Saraç,

Hao

et al. 2024

Adv Synth Catal

View full text Add to dashboard Cite

show abstract

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Catalytic stereoselective Mannich-type reactions for construction of fluorinated compounds

Cited by 1 publication

References 210 publications

Functionalized α‐Fluorinated Amines from Imines and Enol Ethers

Functionalized α‐Fluorinated Amines from Imines and Enol Ethers

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