2008
DOI: 10.4028/www.scientific.net/msf.587-588.538
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Catalytic Performance of Copper-Substituted Polyoxotungstate Materials and X-Ray Structure of a New Sandwich-Type Compound

Abstract: Mono-substituted and sandwich-type copper substituted polyoxoanions ([PW11CuO39]5− and [Cu4(H2O)2(PW9O34)2]10−) were studied as catalysts for the epoxidation of cyclooctene and geraniol, using the green oxidant H2O2, with the results suggesting good efficiency at room temperature. High selectivity and reasonable conversion data were found after the first minutes of reaction. The copper centre may be responsible for this performance and our on-going research focuses in the preparation of new materials incorpora… Show more

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