Catalytic oxidation of tetrabromobisphenol A by iron(III)-tetrakis(p-sulfonatephenyl)porphyrin catalyst supported on cyclodextrin polymers with potassium monopersulfate

Miyamoto, Takafumi; Igrashi, Mami; Kodama, Ritsu; Maeno, Shohei; Fukushima, Masami

doi:10.1016/j.molcatb.2015.06.002

Cited by 14 publications

(6 citation statements)

References 45 publications

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“…In their other contribution, three‐dimensionally cross‐linked CD polymers were tested in a comparative study performed at pH 8 [208] . αCD and γCD proved to be more efficient than βCD both in TBBPA decomposition (full degradation in 1 h vs 96 % in 4 h) and the release of Br − (28.5 μM vs 20 μM).…”

Section: Degradation Of Pollutantsmentioning

confidence: 99%

Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

Molnár

2020

ChemCatChem

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Cyclodextrins are green, environmentally benign products available through the enzymatic degradation of starch for a multitude of varied applications. This review attempts to collect useful information with respect to catalytic studies performed with the use of cyclodextrin and modified cyclodextrin preparations applied in combination of or loaded with varied catalytically active species including metal ions, complexes, and metal particles. Major sections are about their use in hydrogenation, reduction, oxidation, hydroformylation and coupling reactions. Additional sections include their utilization in ring formation and ring opening as well as degradation of pollutants. In the last part, examples about ester hydrolysis, hydroboration and hydrosilylation, as well as hydrogen production are treated. Data collected and analyzed indicate the importance and high potential of cyclodextrin-based catalysts in sustainable chemistry.

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Section: Degradation Of Pollutantsmentioning

confidence: 99%

Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

Molnár

2020

ChemCatChem

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“…Several cyclodextrin derivatives also bind Fe IIItetrakis(p-sulfonatophenyl)porphyrin (Fe III TPPS), and the resulting systems were used as a catalyst for degradation of pentachlorophenol and tetrabromobisphenol A [110][111][112][113][114][115]. In this case cyclodextrins played an important role in preventing the degradation of the porphyrin catalyst.…”

Section: Supramolecular Architectures For Oxygen-mediated Catalysismentioning

confidence: 99%

Heterocomponent ternary supramolecular complexes of porphyrins: A review

Prigorchenko

Ustrnul

Borovkov

et al. 2019

J. Porphyrins Phthalocyanines

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Porphyrins are prominent host molecules which are widely used due to their structural characteristics and directional interaction sites. This review summarizes non-covalently bound ternary complexes of porphyrins, constructed from at least three non-identical species. Progress in supramolecular chemistry allows the creation of complex molecular machinery tools, such as rotors, motors and switches from relatively simple structures in a single self-assembly step. In the current review, we highlight the collection of sophisticated molecular ensembles including sandwich-type complexes, cages, capsules, tweezers, rotaxanes, and supramolecular architectures mediating oxygen-binding and oxidation reactions. These diverse structures have high potential to be applied in sensing, production of new smart materials as well as in medical science.

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“…Polluting phenolics and humic substances have been also suggested as substrates for synthetic metalloporphyrins, in an intriguing series of papers dealing with the development of processes for the treatment of polluted soils [124,125,126,127,128]. Dehalogenation of halogenated phenols, mimicking chloroperoxidases has been also described [129,130,131,132,133].…”

Section: Synthetic Metalloporphyrinsmentioning

confidence: 99%

Immobilized Lignin Peroxidase-Like Metalloporphyrins as Reusable Catalysts in Oxidative Bleaching of Industrial Dyes

et al. 2016

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Synthetic and bioinspired metalloporphyrins are a class of redox-active catalysts able to emulate several enzymes such as cytochromes P450, ligninolytic peroxidases, and peroxygenases. Their ability to perform oxidation and degradation of recalcitrant compounds, including aliphatic hydrocarbons, phenolic and non-phenolic aromatic compounds, sulfides, and nitroso-compounds, has been deeply investigated. Such a broad substrate specificity has suggested their use also in the bleaching of textile plant wastewaters. In fact, industrial dyes belong to very different chemical classes, being their effective and inexpensive oxidation an important challenge from both economic and environmental perspective. Accordingly, we review here the most widespread synthetic metalloporphyrins, and the most promising formulations for large-scale applications. In particular, we focus on the most convenient approaches for immobilization to conceive economical affordable processes. Then, the molecular routes of catalysis and the reported substrate specificity on the treatment of the most diffused textile dyes are encompassed, including the use of redox mediators and the comparison with the most common biological and enzymatic alternative, in order to depict an updated picture of a very promising field for large-scale applications.

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Catalytic oxidation of tetrabromobisphenol A by iron(III)-tetrakis(p-sulfonatephenyl)porphyrin catalyst supported on cyclodextrin polymers with potassium monopersulfate

Cited by 14 publications

References 45 publications

Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

Heterocomponent ternary supramolecular complexes of porphyrins: A review

Immobilized Lignin Peroxidase-Like Metalloporphyrins as Reusable Catalysts in Oxidative Bleaching of Industrial Dyes

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