Catalytic hydrocracking of vegetable oil for agrofuels production using Ni–Mo, Ni–W, Pt and TFA catalysts supported on SBA-15

C., A.E. Barrón; Melo-Banda, J.A.; E., J.M. Dominguez; M., E. Hernández; R., R. Silva; T., A.I. Reyes; M., M.A. Meraz

doi:10.1016/j.cattod.2011.01.026

Cited by 42 publications

(24 citation statements)

References 25 publications

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“…The metal oxide should be reduced to obtain an active metallic phase, i.e. Co and Ni, as reported in previous study [12,13]. The metals content measured by atomic absorption spectrometry (AAS) was 3.55 wt.% Co and 3.30 wt.% Ni of the total catalyst weight.…”

Section: Procedures and Instrumentationmentioning

confidence: 88%

“…The result from GC-MS compared to the GC-MS result of commercial fuel from the refueling public [14]. It was divided into three fraction such as gasoline-like hydrocarbon (C 5 -C 9 ), kerosene-like hydrocarbon (C 10 -C 13 ), and gasoillike hydrocarbon (C 14 -C 22 ) [6,13]. By using the Wiley275 and NIST02 mass spectral library of data, all hydrocarbon compounds were identified.…”

Section: Procedures and Instrumentationmentioning

confidence: 99%

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Co-Ni/HZSM-5 Catalyst for Hydrocracking of Sunan Candlenut Oil (Reutealis trisperma (Blanco) Airy Shaw) for Production of Biofuel

Muttaqii

Marlinda

Roesyadi

et al. 2017

J. Pure App. Chem. Res.

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The production of biofuel by hydrocracking of Sunan candlenut oil as renewable energy can substitute fossil energy. The purpose of this work is to produce biofuel by hydrocracking of Sunan candlenut oil with Co-Ni/HZSM-5 catalyst. The catalyst was prepared by incipient wetness impregnation method. The characterization of catalyst was determined by X-Ray Diffraction (XRD) and nitrogen adsorption-desorption isotherms. The functional groups of the hydrocarbon was determined by Fourier Transform Infrared (FT-IR). The hydrocarbon composition was determined by Gas Chromatography Mass Spectrometry (GC-MS). The results showed that biofuel composition consist of 0.14 area% isoparaffins, 12.29 area% cycloparaffins, 6.87 area% normal paraffins, 4.18 area% olefin, and 10.52 area% aromatics, and oxygenated compounds including 35.03 area% carboxylic acids. It was necessary to be done that the oxygenated compounds in biofuel were eliminated to produce the abundant paraffin hydrocarbons at reaction temperature above 350 o C.

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Section: Procedures and Instrumentationmentioning

confidence: 88%

Section: Procedures and Instrumentationmentioning

confidence: 99%

Co-Ni/HZSM-5 Catalyst for Hydrocracking of Sunan Candlenut Oil (Reutealis trisperma (Blanco) Airy Shaw) for Production of Biofuel

Muttaqii

Marlinda

Roesyadi

et al. 2017

J. Pure App. Chem. Res.

View full text Add to dashboard Cite

show abstract

“…The hydrocarbon components with a probility match equal to or higher than 80% were considered. N-paraffin, aromatic, cyloparaffin, and olefin contained in liquid product were grouped as gasoline-like hydrocarbon (C5-C9), kerosene-like hydrocarbon (C10-C13), and gasoil-like hydrocarbon (C14-C22), as reported by Barron et al [15].…”

Section: Hydrocracking Processmentioning

confidence: 95%

Formation of hydrocarbon compounds during the hydrocracking of non-edible vegetable oils with cobalt-nickel supported on hierarchical HZSM-5 catalyst

Marlinda

Muttaqii

Roesyadi

et al. 2017

IOP Conf. Ser.: Earth Environ. Sci.

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“…Hydrocarbons (i.e. paraffin, aromatic, cyloparaffin, and olefin) contained in biofuel were defined as gasolinelike hydrocarbon (C5-C9), kerosene-like hydrocarbon (C10-C13), and gasoil-like hydrocarbon (C14-C22), as reported by Barron et al [25]. The liquid hydrocarbon product of Ceiba pentandra oil were performed by GC-MS and Fourier Transformed Infra Red (FTIR) spectroscopy analyses.…”

Section: Product Analysismentioning

confidence: 99%

Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil

Mirzayanti

Kurniawansyah

Prayitno

et al. 2017

Bull. Chem. React. Eng. Catal.

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Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400 o C for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400 o C. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel.

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Catalytic hydrocracking of vegetable oil for agrofuels production using Ni–Mo, Ni–W, Pt and TFA catalysts supported on SBA-15

Cited by 42 publications

References 25 publications

Co-Ni/HZSM-5 Catalyst for Hydrocracking of Sunan Candlenut Oil (Reutealis trisperma (Blanco) Airy Shaw) for Production of Biofuel

Co-Ni/HZSM-5 Catalyst for Hydrocracking of Sunan Candlenut Oil (Reutealis trisperma (Blanco) Airy Shaw) for Production of Biofuel

Formation of hydrocarbon compounds during the hydrocracking of non-edible vegetable oils with cobalt-nickel supported on hierarchical HZSM-5 catalyst

Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil

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