Serial difunctional catalysts supported
on γ-Al2O3 and HY zeolites were synthesized
and characterized
systemically. The characterization results revealed that hydrogen
spillover existed in NiMo and CoMo catalysts, and decreasing Ni/Mo
and Co/Mo ratios could reduce hydrogen spillover. Meanwhile, the naphthalene
hydrocracking behaviors over different catalysts were investigated
and compared. The higher yield of cyclane for CoMo/AY catalysts demonstrated
that hydrogen spillover could deeply hydrogenate naphthalene into
cyclane. The combined catalysts Ni/Y@CoMo/A, Ni/Y@NiMo/A, and Ni/Y@Mo/A
showed relatively lower conversions of naphthalene but higher yields
of valued