Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

Beasley, Charles H.; Duletski, Olivia L.; Stankevich, Ksenia S.; Arulsamy, Navamoney; Mock, Michael T.

doi:10.1039/d4dt00702f

Dalton Trans.

2024

DOI: 10.1039/d4dt00702f

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Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N₂)₂(diphosphine)₂ complexes

Charles H. Beasley,

Olivia L. Duletski,

Ksenia S. Stankevich

et al.

Abstract: We report the synthesis and characterization of trans-[Cr(N2)2(depe)2] (depe = Et2PCH2CH2PEt2). trans-[Cr(N2)2(depe)2] and the structurally similar complex trans-[Cr(N2)2(dmpe)2] (dmpe = Me2PCH2CH2PMe2) catalyze the reduction of N2 to form N2H4 and...

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Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis

Duletski,

Platz,

Pollock

et al. 2024

Chem. Commun.

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Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis

Duletski,

Platz,

Pollock

et al. 2024

Chem. Commun.

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Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N₂)₂(diphosphine)₂ complexes

Abstract: We report the synthesis and characterization of trans-[Cr(N2)2(depe)2] (depe = Et2PCH2CH2PEt2). trans-[Cr(N2)2(depe)2] and the structurally similar complex trans-[Cr(N2)2(dmpe)2] (dmpe = Me2PCH2CH2PMe2) catalyze the reduction of N2 to form N2H4 and...

Cited by 1 publication

References 47 publications

Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis

Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis

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Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

Abstract: We report the synthesis and characterization of trans-[Cr(N2)2(depe)2] (depe = Et2PCH2CH2PEt2). trans-[Cr(N2)2(depe)2] and the structurally similar complex trans-[Cr(N2)2(dmpe)2] (dmpe = Me2PCH2CH2PMe2) catalyze the reduction of N2 to form N2H4 and...

Cited by 1 publication

References 47 publications

Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis

Dinitrogen activation at chromium by photochemically induced CrII–C bond homolysis

Contact Info

Product

Resources

About

Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N₂)₂(diphosphine)₂ complexes

Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis

Dinitrogen activation at chromium by photochemically induced Cr^II–C bond homolysis