2003
DOI: 10.1016/s0926-3373(02)00307-7
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Catalytic conversion of methane to acetylene induced by microwave irradiation

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Cited by 18 publications
(9 citation statements)
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“…MW photocatalytic degradation using EDLs had received increasing interests in photochemical reactions in recent years. Klán et al [13][14][15][16][17][18] studied the photoreduction of acetophenone, photolysis of a phenacyl ester, etc., by modified domestic MW oven integrated EDLs and found that it was possible for photodegradation of environmentally unwanted compounds as its reasonable photochemical efficiency and other advantages. MW photocatalytic degradation was superior for its simple device, simultaneous effects of UV-vis light and MW electromagnetic radiation and EDLs in wireless way.…”
Section: Introductionmentioning
confidence: 99%
“…MW photocatalytic degradation using EDLs had received increasing interests in photochemical reactions in recent years. Klán et al [13][14][15][16][17][18] studied the photoreduction of acetophenone, photolysis of a phenacyl ester, etc., by modified domestic MW oven integrated EDLs and found that it was possible for photodegradation of environmentally unwanted compounds as its reasonable photochemical efficiency and other advantages. MW photocatalytic degradation was superior for its simple device, simultaneous effects of UV-vis light and MW electromagnetic radiation and EDLs in wireless way.…”
Section: Introductionmentioning
confidence: 99%
“…In the early 1990s, the group of Wan and coworkers at Queens University in Canada worked on the application of bursts of microwave energy to catalytic systems [139,140,141,34,142]. To realize this they used catalytic particles (metal) which are sensitive to microwave radiation.…”
Section: Results By Wan and Coworkersmentioning
confidence: 99%
“…For instance, Wan mentions that "'In an ideal situation, one would have an instant, transient high temperature to provide the energy for chemical activation and immediately after the primary reaction (which usually is less than a microsecond) the temperature is cooled off below the activation barrier to minimize any secondary reactions leading to undesirable products."' Furthermore, they also mention the possibility of controlling the rate of reaction/selectivity by shaping the energy pulses [34,142].…”
Section: Results By Wan and Coworkersmentioning
confidence: 99%
“…Recently, microwave‐accelerated catalytic reactions have aroused tremendous attention because they show a drastic enhancement on catalytic reaction rate and selectivity under mild conditions . Furthermore, some chemical reactions that are impossible in the CRM can be performed successfully under the microwave reaction mode .…”
Section: Introductionmentioning
confidence: 99%
“…Recently,m icrowave-accelerated catalytic reactions have aroused tremendous attention because they show ad rastic enhancemento nc atalytic reaction rate and selectivityu nder mild conditions. [20][21][22][23][24][25][26][27][28] Furthermore, some chemical reactions that are impossible in the CRMc an be performed successfully under the microwave reactionm ode. [29][30][31][32][33] This significant microwave effect may provide anew approach to address the followingt wo main challenges for NO decomposition over metal oxide catalysts at ah igh reactiont emperatures and with strong oxygen inhibition.…”
Section: Introductionmentioning
confidence: 99%