Catalytic Conversion of Furfural into a 2,5‐Furandicarboxylic Acid‐Based Polyester with Total Carbon Utilization

Pan, Tao; Deng, Jin; Xu, Qing; Zuo, Yi; Guo, Qi; Fu, Yao

doi:10.1002/cssc.201200652

Cited by 107 publications

(95 citation statements)

References 48 publications

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“…Biomass comprising of 75% carbohydrates is the only renewable source available widely, which has the potential to replace current non-renewable fossil resources. Now-a-days, most attractive and promising approach is to convert biomass derived carbohydrates to furanic aldehydes such as HMF as it is a promisable candidate and serves as a platform compound for fine chemicals, plasticizers and polymers [1][2][3][4][5][6][7][8][9][10]. As seen from the literature, dehydration of fructose into HMF is very easy and efficient [11].…”

Section: Introductionmentioning

confidence: 99%

Biomass derived β-cyclodextrin-SO 3 H carbonaceous solid acid catalyst for catalytic conversion of carbohydrates to 5-hydroxymethylfurfural

Thombal

Jadhav

2015

Applied Catalysis A: General

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Section: Introductionmentioning

confidence: 99%

Biomass derived β-cyclodextrin-SO 3 H carbonaceous solid acid catalyst for catalytic conversion of carbohydrates to 5-hydroxymethylfurfural

Thombal

Jadhav

2015

Applied Catalysis A: General

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“…FDCA is produced from hydroxymethyl‐furfural, derived from renewable sources. Among the properties of PEF that attracted recent attention is its higher glass temperature ( T g ), lower melting temperature ( T m ), higher tensile modulus, and, more importantly, improved gas barrier properties as compared to poly(ethylene terephthlate) (PET) . The first report on 2,5‐FDCA‐based polyesters is a patent from 1946 by British Celanese .…”

Section: Introductionmentioning

confidence: 99%

Molecular Dynamics of Poly(ethylene‐2,5‐furanoate) (PEF) as a Function of the Degree of Crystallinity by Dielectric Spectroscopy and Calorimetry

Dimitriadis

Bikiaris

Papageorgiou

et al. 2016

Macro Chemistry & Physics

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The segmental and local dynamics of the bio‐based polyester poly(ethylene‐2,5‐furanoate) (PEF) are investigated by dielectric spectroscopy (DS) at atmospheric pressure as a function of temperature and frequency for samples prepared with different degrees of crystallinity. Crystallization significantly alters the segmental process as this is manifested in the dielectric strength and the distribution of relaxation times. Enhanced crystallinity by the different annealing protocols increases the glass temperature of the mobile amorphous fraction. A two‐phase model is adequate in describing the dynamics associated with the β‐process within the glassy state. However, the same model fails in describing the segmental dynamics at and above the glass temperature. The combined differential scanning calorimetry and DS results provide evidence that for samples with a degree of crystallinity of ≈40%, approximately a third of segments are located within the restricted amorphous fraction.

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“…Conversion of C6-sugars into FDCA. FDCA based co(polyesters) FDCA + Ethylene glycol + 1,4-butylene glycol [159] PET-ran-PEF copolyesters bis(hydroxyethyl)-2,5-furandicarboxylate + bis(2-hydroxyethyl) terephthalate [160] Poly(butylene 2,5-furandicarboxylate) FDCA + 1,4-butanediol [161] Poly(octylene furanoate) DMFD + 1,8-octamethylenediol [162] Poly(butylene succinate-co-butylene furandicarboxylate) copolyesters FDCA + Succinic acid + 1,4-butanediol [163] Thermoplastic aromatic polyesters vanillin + fatty acid derivatives [167] poly(caffeic acid-co-lithocholic acid) caffeic and lithocholic acids [168] poly(caffeic acid-co-hydroxycapric acid) caffeic and hydroxycapric acids [169] (1) Obtained by reaction between vanillin and acetic anhydride.…”

Section: ) Lignin-based Polyestersmentioning

confidence: 99%

Recent Strategies for the Development of Biosourced-Monomers, Oligomers and Polymers-Based Materials: A Review with an Innovation and a Bigger Data Focus

Rebouillat¹,

Pla²

2016

JBNB

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After setting the ground of the quantum innovation potential of biosourced entities and outlining the inventive spectrum of adjacent technologies that can derive from those, the current review highlights, with the support of Bigger Data approaches, and a fairly large number of articles, more than 250 and 10,000 patents, the following. It covers an overview of biosourced chemicals and materials, mainly biomonomers, biooligomers and biopolymers; these are produced today in a way that allows reducing the fossil resources depletion and dependency, and obtaining environmentallyfriendlier goods in a leaner energy consuming society. A process with a realistic productivity is underlined thanks to the implementation of recent and specifically effective processes where engineered microorganisms are capable to convert natural non-fossil goods, at industrial scale, into fuels and useful high-value chemicals in good yield. Those processes, further detailed, integrate: metabolic engineering involving 1) system biology, 2) synthetic biology and 3) evolutionary engineering. They enable acceptable production yield and productivity, meet the targeted chemical profiles, minimize the consumption of inputs, reduce the production of by-products and further diminish the overall operation costs. As generally admitted the properties of most natural occurring biopolymers (e.g., starch, poly (lactic acid), PHAs.) are often inferior to those of the polymers derived from petroleum; blends and composites, exhibiting improved properties, are now successfully produced. Specific attention is paid to these aspects. Then further evidence is provided to support the important potential and role of products deriving from the biomass in general. The need to en- ter into the era of Bigger Data, to grow and increase the awareness and multidimensional role and opportunity of biosourcing serves as a conclusion and future prospects. Although providing a large reference database, this review is largely initiatory, therefore not mimicking previous classic reviews but putting them in a multiplying synergistic prospective.

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Catalytic Conversion of Furfural into a 2,5‐Furandicarboxylic Acid‐Based Polyester with Total Carbon Utilization

Cited by 107 publications

References 48 publications

Biomass derived β-cyclodextrin-SO 3 H carbonaceous solid acid catalyst for catalytic conversion of carbohydrates to 5-hydroxymethylfurfural

Biomass derived β-cyclodextrin-SO 3 H carbonaceous solid acid catalyst for catalytic conversion of carbohydrates to 5-hydroxymethylfurfural

Molecular Dynamics of Poly(ethylene‐2,5‐furanoate) (PEF) as a Function of the Degree of Crystallinity by Dielectric Spectroscopy and Calorimetry

Recent Strategies for the Development of Biosourced-Monomers, Oligomers and Polymers-Based Materials: A Review with an Innovation and a Bigger Data Focus

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