2023
DOI: 10.1002/slct.202204715
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Catalytic Chemical Vapor Deposition Methodology for Carbon Nanotubes Synthesis

Man Vir Singh,
Ajay Kumar Tiwari,
Rajeev Gupta

Abstract: Carbon nanomaterial is a smart material of the 21st century. This review encompasses various studies involved in carbon nanotube synthesis (CNTs) (Single and multi‐walled) using the catalytic chemical vapor deposition method (CVD). Due to their structural features, the promising branch of nanotechnology is that CNTs possess electrical, magnetic, thermal, chemical, mechanical, and optical properties. 90 to 99 % CNTs were synthesized by the CVD method (Tip growth model and Base growth model) while 80 to 80 % wer… Show more

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Cited by 17 publications
(4 citation statements)
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“…The formation of graphene layers surrounding the metal cluster can be explained on the basis of catalyst-substrate interaction. According to the well-known tip-growth model of carbon nanotube (CNT) formation, 53 when the catalystsubstrate interaction is weak, the dissolved carbon atoms can precipitate out across the metal bottom, pushing the whole metal particle off the substrate. In the growth of graphene here, as the Mo has strong carbide-forming ability, carbon atoms dissolving into the Mo clusters lead to the formation of stable Mo 2 C first and subsequently precipitate out and crystallize in the form of graphene layers once the solubility limit is attained.…”
Section: Resultsmentioning
confidence: 99%
“…The formation of graphene layers surrounding the metal cluster can be explained on the basis of catalyst-substrate interaction. According to the well-known tip-growth model of carbon nanotube (CNT) formation, 53 when the catalystsubstrate interaction is weak, the dissolved carbon atoms can precipitate out across the metal bottom, pushing the whole metal particle off the substrate. In the growth of graphene here, as the Mo has strong carbide-forming ability, carbon atoms dissolving into the Mo clusters lead to the formation of stable Mo 2 C first and subsequently precipitate out and crystallize in the form of graphene layers once the solubility limit is attained.…”
Section: Resultsmentioning
confidence: 99%
“…The third technique to manufacture CNTs is known as Chemical Vapor Deposition (CVD) method. This technique uses a carbon source along with a catalyst and produces CNTs having irregular and dispersed graphene sheaths ( 30 ). CVD uses hydrogen gas and other processed gases such as N 2 and H 2 .…”
Section: Manufacturing and Characterization Of Cntsmentioning
confidence: 99%
“…Once carbon enters the gas phase, the nucleation and growth of carbon structures occur. These structures grow into carbon nanotubes through self-assembly phenomena, sometimes aided by iron nanoparticles and under specific conditions of pressure, temperature, gas mixture, and power [7].…”
Section: Conservative Power Theory (Cpt)mentioning
confidence: 99%