Catalytic Application of POSS–COF-[(Co(acetate)2] for Selective Reduction of Nitriles to Amines
Anosha Rubab,
Manzar Sohail,
Riyadh H. Alshammari
et al.
Abstract:We report the reticular synthesis and structural investigations through the spectroscopic analysis of a novel polyhedral oligomeric silsesquioxane (POSS)-modified framework, hereby ascribed as a catalyst for the selective reduction of aryl nitriles to amines. The integration of the unique features of the polyhedral oligomeric silsesquioxane with 2,2′-Bipyridine-4,4′-dicarboxaldehyde and subsequently coordination to cobalt acetate manifests a distinctive feature, which is a stable covalent bond between Co and t… Show more
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