Catalytic and electrocatalytic conversion of glucose into value-added chemicals

Lee, Jechan; Jung, Sungwook; Kim, Yong Tae; Kim, Hyung Ju; Kim, Ki‐Hyun

doi:10.1016/j.rser.2023.113337

Cited by 9 publications

(5 citation statements)

References 98 publications

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“…glucose) in electrolyte solutions and are not competitive economically for reduction compared with chemo-catalytic hydrogenation schemes. 35 Photo-catalytic methods for cellulose conversion have been explored in recent years to make reaction conditions mild and sustainable. 36 Of the methods shown in Table 1, chemo-catalysis offers both broad scope and scalability for the many kinds of lignocellulosic biomass substrates that need to be addressed.…”

Section: Catalytic Systems For Sorbitol Productionmentioning

confidence: 99%

Chemocatalytic production of sorbitol from cellulose via sustainable chemistry – a tutorial review

Zhou,

Smith,

2024

Green Chem.

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Section: Catalytic Systems For Sorbitol Productionmentioning

confidence: 99%

Chemocatalytic production of sorbitol from cellulose via sustainable chemistry – a tutorial review

Zhou,

Smith,

2024

Green Chem.

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“…In recent times, there has been a growing interest in the use of mesoporous silicas, halloysite nanotubes, and other porous materials, including graphitic carbon nitride, as catalyst supports for direct application in catalytic processes . Graphitic carbon nitride, an absorbent material with very high crystallinity, large surface area, low crystal density, tailorable functions, and considerable active junctions, has extensive applications in catalytic conversion, energy storage, and separation sectors. , Nowadays, there is a lot of research on converting carbohydrates into valuable products using different catalysts . However, it is essential to note that in biomass conversion processes the reactions often result in the formation of a mixture of products.…”

Section: Introductionmentioning

confidence: 99%

Efficient Conversion of Carbohydrates into 5-Hydroxymethylfurfural Using Graphitic Carbon Nitride Bearing Brönsted Acid Sites

Le,

Nguyen,

Le Nguyen

et al. 2024

Energy Fuels

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The current focus in biomass conversion research is to achieve high yields and selectivity of 5-hydroxymethylfurfural (HMF) as a platform chemical from renewable sources, emphasizing the need for a sustainable and efficient heterogeneous acid catalyst. The goal is to develop a low-cost, energy-efficient approach that aligns with sustainability principles. In this work, graphitic carbon nitride bearing Bronsted acid sites (g-C 3 N 4 − SO 3 H) was synthesized and applied as a catalyst for converting carbohydrates into HMF in dimethyl sulfoxide (DMSO) as a solvent. The catalyst structure was determined using modern spectroscopic techniques such as Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution X-ray photoelectron spectrometry (HRXPS), transmission electron microscopy (TEM), and Brunauer− Emmett−Teller (BET), and thermogravimetric analysis (TGA) evaluated the stability of the catalyst. In order to optimize the reaction efficiency, several factors were examined, such as the temperature, solvents, catalyst mass, and reaction time. These parameters were carefully studied and adjusted in order to optimize the reaction conditions. As a result, the reaction yield was highest at about 60% HMF after 3 h at 120 °C with g-C 3 N 4 −SO 3 H (30 mg) using fructose as the substrate. The combination of AlCl 3 and g-C 3 N 4 −SO 3 H gave an excellent yield, which accounted for 58% of HMF from glucose at 3 h at 120 °C. Additionally, the catalyst employed in our study can be easily recovered and reused for subsequent reactions. Our research presents a straightforward and efficient procedure for synthesizing the catalyst, enabling the conversion of glucose or fructose into 5-hydroxymethylfurfural (HMF) with a high yield within a short reaction time.

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“…4,5 As the most widespread and cheapest biomassderived component, glucose can be used to synthesize a wide range of value-added chemicals. [6][7][8][9] Among others, 5-hydroxymethylfurfural (HMF) has been listed as one of the "top 10 + 4" bio-based platform chemicals as an addition to the original list from the U.S. Department of Energy (DOE). 10 The highly selective transformation of glucose to HMF has become one of the key steps for the efficient utilization of biomass-derived carbons.…”

Section: Introductionmentioning

confidence: 99%

A universal solvent effect on the formation of soluble humins in glucose dehydration to 5-hydroxymethylfurfural

Li,

Min,

et al. 2024

React. Chem. Eng.

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Catalytic and electrocatalytic conversion of glucose into value-added chemicals

Cited by 9 publications

References 98 publications

Chemocatalytic production of sorbitol from cellulose via sustainable chemistry – a tutorial review

Chemocatalytic production of sorbitol from cellulose via sustainable chemistry – a tutorial review

Efficient Conversion of Carbohydrates into 5-Hydroxymethylfurfural Using Graphitic Carbon Nitride Bearing Brönsted Acid Sites

A universal solvent effect on the formation of soluble humins in glucose dehydration to 5-hydroxymethylfurfural

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