“…Over the past 5-10 years, we have been actively engaged in research of the cycloaddition reaction between diazo compounds and [60]fullerene under catalytic conditions and found that among the tested complexes and salts of Cu, Pd and Rh a three-component catalytic system Pd(acac) 2 -PPh 3 -Et 3 Al has the greatest efficiency and selectivity in the reactions of C 60 with the simplest diazoalkanes, 5 diazoacetates, 6,7 and diazoketones 8 to promote the selective formation of the corresponding homo-or methanofullerenes. Herein, we attempted to explore the application boundaries of the cycloaddition reaction of diazo compounds to C 60 in the presence of Pd(acac) 2 -PPh 3 -Et 3 Al catalyst on the example of symmetric and asymmetric diazoalkanes and also higher diazoacetates of various structure.…”