Catalyst‐Controlled 1,3‐Polyol Syntheses

Harschneck, Tobias; Kirsch, Stefan F.

doi:10.1002/9783527652235.ch23

Asymmetric Synthesis II 2012

DOI: 10.1002/9783527652235.ch23

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Catalyst‐Controlled 1,3‐Polyol Syntheses

Tobias Harschneck

Stefan F. Kirsch

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Cited by 3 publications

References 46 publications

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Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Holt

Gaunt

2015

Angewandte Chemie

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A novel method for the synthesis of a wide range of functionalized 1,3‐diol derivatives is reported. Employing a copper‐catalyzed oxy‐alkenylation strategy, a range of readily available, substituted homoallylic alcohol derivatives and alkenyl(aryl) iodonium salts combine to form syn‐1,3‐carbonates in excellent yield and with high selectivity. Furthermore, the products formed are amenable to an iterative reaction sequence, thus affording highly complex polyketide‐like fragments.

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Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Holt

Gaunt

2015

Angewandte Chemie

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show abstract

Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Holt

Gaunt

2015

Angew Chem Int Ed

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A novel method for the synthesis of a wide range of functionalized 1,3-diol derivatives is reported. Employing a copper-catalyzed oxy-alkenylation strategy, a range of readily available, substituted homoallylic alcohol derivatives and alkenyl(aryl) iodonium salts combine to form syn-1,3-carbonates in excellent yield and with high selectivity. Furthermore, the products formed are amenable to an iterative reaction sequence, thus affording highly complex polyketide-like fragments.

show abstract

Catalytic strategies towards 1,3-polyol synthesis by enantioselective cascades creating multiple alcohol functions

2020

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Catalyst‐Controlled 1,3‐Polyol Syntheses

Cited by 3 publications

References 46 publications

Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Copper‐Catalyzed Oxy‐Alkenylation of Homoallylic Alcohols to Generate Functional syn‐1,3‐Diol Derivatives

Catalytic strategies towards 1,3-polyol synthesis by enantioselective cascades creating multiple alcohol functions

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