Catalysis by Homo‐ and Heteronuclear Polymetallic Systems

Моисеев, И. И.; Гехман, А. Е.; Цодиков, М. В.; Kugel, V. Ya.; Yandieva, F. A.; Glebov, L. S.; Kliger, G. Yu.; Mikaya, A. I.; Заикин, В. Г.; Maksimov, Yu. V.; Kochubey, D.I.; Кривенцов, В. В.; Mordovin, V. P.; Navı́o, J.A.

doi:10.1002/3527603557.ch11

Cited by 3 publications

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“…For instance, 64% of ethanol was converted giving rise to mostly C 1 -C 4 alkanes and 4.5% mol C 5 -C 10 alkanes (see Experimental and [13].…”

Section: Ethanol Conversion Over Intermetallic Hydride and Co-catalystsmentioning

confidence: 99%

“…Alkanes C 5 -C 8 predominated in the alkane fraction [13]. In this paper the ethanol reaction is discussed in more detail.…”

Section: Introductionmentioning

confidence: 99%

“…Recently, a new catalytic reaction, alcohol reductive conversion into alkanes with at least doubled number of carbon atoms compared to the initial alcohol was reported [12,13]. For instance, cyclopentanol was found to react with dihydrogen at 250°C in the presence of an iron catalyst giving rise to a mixture of hydrocarbons containing cyclopentanyl and cyclopentanylidene fragments (see Scheme 1):…”

Section: Introductionmentioning

confidence: 99%

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Reductive Dehydration of Ethanol: A New Route Towards Alkanes

et al. 2007

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New reactions, catalytic ethanol reductive dehydration into alkanes C 3 -C 10 and cross-coupling of ethanol with cyclopentanol into alkyl substituted cycloalkanes, were studied. The reductive dehydration of ethanol was carried out at 350°C and 50 atm of Ar. The intermetallic hydrides with different hydrogen content, industrial Pt/c-Al 2 O 3 and reduced molten promoted iron catalysts were used as catalysts. The yield of alkanes varies depending on acid/base additives. The conversion of ethanol and the yield of higher alkanes increase as the hydrogen content in the intermetallic material decreases. When MgO is used as additive ethanol converts mainly into iso-alkanes. The content of iso-alkanes in the C 5 -C 10 fraction reaches 92%. The cross-coupling of ethanol with cyclopentanol over the catalytic compositions consisting of intermetallic hydride and Pt/c-Al 2 O 3 and reduced molten promoted iron afforded cyclic alkyl substituted hydrocarbons.

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“…For instance, 64% of ethanol was converted giving rise to mostly C 1 -C 4 alkanes and 4.5% mol C 5 -C 10 alkanes (see Experimental and [13].…”

Section: Ethanol Conversion Over Intermetallic Hydride and Co-catalystsmentioning

confidence: 99%

“…Alkanes C 5 -C 8 predominated in the alkane fraction [13]. In this paper the ethanol reaction is discussed in more detail.…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Reductive Dehydration of Ethanol: A New Route Towards Alkanes

et al. 2007

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Catalysis by Homo‐ and Heteronuclear Polymetallic Systems

et al. 2006

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Heterometallic Palladium(II)–Indium(III) and −Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation

et al. 2018

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The reaction of Pd(OOCMe) with indium(III) and gallium(III) acetates was studied to prepare new Pd-based heterometallic carboxylate complexes with group 13 metals. The heterometallic palladium(II)-indium(III) acetate-bridged complexes Pd(OOCMe)In(OOCMe) (1) and Pd(OOCMe)In(OOCMe)·MeCOOH (1a) were synthesized and structurally characterized with X-ray crystallography and extended X-ray absorption fine structure in the solid state and solution. A similar Pd-Ga heterometallic complex formed by the reaction of Pd(OOCMe) with gallium(III) acetate in a dilute acetic acid solution, as evidenced by atmospheric pressure chemical ionization mass and UV-vis spectrometry, was unstable at higher concentrations and in the solid state. Complex 1 catalyzes the liquid-phase-selective phenylacetylene and styrene hydrogenation (1 atm of H at 20 °C) in acetic acid, ethyl acetate, and N, N-dimethylformamide solutions, while no Pd metal was formed until alkyne and alkene hydrogenation ceased.

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Catalysis by Homo‐ and Heteronuclear Polymetallic Systems

Cited by 3 publications

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Reductive Dehydration of Ethanol: A New Route Towards Alkanes

Reductive Dehydration of Ethanol: A New Route Towards Alkanes

Catalysis by Homo‐ and Heteronuclear Polymetallic Systems

Heterometallic Palladium(II)–Indium(III) and −Gallium(III) Acetate-Bridged Complexes: Synthesis, Structure, and Catalytic Performance in Homogeneous Alkyne and Alkene Hydrogenation

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