Catalysis and Synthesis Enabled by P-Chiral Dihydrobenzooxaphosphole Ligands
Zhen Cao,
Dongyang He,
Wenjun Tang
Abstract:P-Chiral phosphorus ligands received little attention in organic chemistry until Knowles made his landmark contribution in asymmetric hydrogenation by developing the P-chiral ligands CAMP and DIPAMP. The development of P-chiral phosphorus ligands accelerated in the end of the last century with the advent of some highly efficient and renowned ligands for asymmetric hydrogenation, including BisP*, TangPhos, QuinoxP*, DuanPhos, et al. However, most reported ligands were airsensitive, difficult to make, or lacked … Show more
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