Understanding how the Galactic magnetic field threads the multi-phase interstellar medium (ISM) remains a considerable challenge, as different magnetic field tracers probe dissimilar phases and field components. We search for evidence of a common magnetic field shared between the ionized and neutral ISM by comparing 1.4 GHz radio continuum polarization and H i line emission from the Galactic Arecibo L-Band Feed Array Continuum Transit Survey (GALFACTS) and Galactic Arecibo L-Band Feed Array H i (GALFA-H i) survey, respectively. We compute the polarization gradient of the continuum emission and search for associations with diffuse/translucent H i structures. The polarization gradient is sensitive to changes in the integrated product of the thermal electron density and line-ofsight field strength (B ) in warm ionized gas, while narrow H i structures highlight the plane-of-sky field orientation in cold neutral gas. We identified one region in the high-Galactic latitude Arecibo sky, G216+26 centered on ( , b)∼(216 • , +26 • ), containing filaments in the polarization gradient that are aligned with narrow H i structures roughly parallel to the Galactic plane. We present a comparison of multi-phase observations and magnetic field tracers of this region, demonstrating that the warm ionized and cold neutral media are connected likely via a common magnetic field. We quantify the physical properties of a polarization gradient filament associated with Hα emission, measuring a lineof-sight field strength B = 6±4 µG and a plasma beta β = 2.1 +3.1 −2.1 . We discuss the lack of widespread multi-phase magnetic field alignments and consider whether this region is associated with a shorttimescale or physically rare phenomenon. This work highlights the utility of multi-tracer analyses for understanding the magnetized ISM.