Carboxylic and sulfonic N-substituted naphthalene diimide salts as highly stable non-polymeric organic electrodes for lithium batteries

Lakraychi, Alae Eddine; Fahsi, Karim; Aymard, L.; Poizot, Philippe; Dolhem, Franck; Bonnet, Jean-Pierre

doi:10.1016/j.elecom.2017.01.019

Cited by 38 publications

(32 citation statements)

References 25 publications

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“…Rather than using scarce metal elements, the use of environmentally abundant metal elements, such as iron, is a promising option. Moreover, the use of organic compounds as electrode materials is also promising . Using charge carriers other than Li ions, such as sodium, potassium, magnesium, calcium, aluminum, or molecular ions, is another method to develop sustainability in society.…”

Section: Introductionmentioning

confidence: 99%

Analytical Measurements to Elucidate Structural Behavior of 2,5‐Dimethoxy‐1,4‐benzoquinone During Charge and Discharge

et al. 2020

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Section: Introductionmentioning

confidence: 99%

Analytical Measurements to Elucidate Structural Behavior of 2,5‐Dimethoxy‐1,4‐benzoquinone During Charge and Discharge

et al. 2020

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“…Hence, the resistance of corresponding electroactive material has been increased from 350 Ω to 565Ω (Figure b). The highest R ct value is because of the formation of solid electrolyte interface(SEI) layer after thecycling . The obtained minordifference of interface resistance could be attributed to the porous structural assembly .…”

Section: Resultsmentioning

confidence: 99%

Hierarchical Nanostructured Benzoic Naphthalene Tetracarboxylic Di‐imide Organic Cathode for Lithium Ion Battery

Khupse

Bhosale³

et al. 2020

ChemistrySelect

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Organic redox active molecules are the promising electrode materials for the Lithium‐ion batteries (LIBs). The semiconducting nature and morphology of these materials provide more efficient charge transport. Hence, it is very important to perform systematic study of such molecules. Herein, we proposed single step synthesis of the benzoic naphthalene diimide (Benzoic‐NTCDI) by the reaction of 1, 4, 5, 8‐ naphthalene tetracarboxylic dianhydride with 4‐amino benzoic acid in presence of hydrated zinc acetate as a catalyst. As‐synthesized benzoic NTCDI is characterised by using different characterization techniques. The morphological study clearly demonstrate hierarchical porous assembly of 3–5 micron comprised with nanopetals of thickness 5–10 nm. In this hierarchical nanostructure, the nanopetals are originated from the centre and confer voids between the layers of petals. This creates porosity throughout the hierarchical assembly. Considering such unique porous nanostructure and good conductivity of the Benzoic‐NTCDI (1.19×10−5 S/m), it has been used as a cathode for LIB.The Li‐cell was fabricated using Benzoic‐NTCDI as a cathode which demonstrated the reversible capacity of 102 mAhg−1 at 0.05 C rate. Moreover, the capacity of 91 mAhg−1 is retained at current density of 0.1 C exhibiting good rate capability after 24 cycles. The Li‐ion transport has been accelerated is ascribed to the porous hierarchical nanostructure. The potential of one of the heterocyclic molecule with hierarchical nanostructure as a cathode for lithium ion batteries (LIBs) has been demonstrated for the first time

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“…[27c] Similarly to the previously discussed study, and to circumvent the unwanted solubility in usual organic electrolytes of the small molecular weight active materials, Lakraychi et al reported the N-substitution on naphthalene tetra-carboxylic diimide (NDIs) ionic compounds having a carbon chain spacer between the nitrogen atom and the anionic groups, namely, methyl-sodium carboxylate (NTCDI(MeCarb-Na) 2 ) 10 and ethylsodium sulfonate (NTCDI(EtSulf-Na) 2 ) 11 salts. [32] The two molecules were synthesized by reaction of naphthalene tetracarboxylic di-anhydride 4 with neutralized glycine and taurine, in 90 % and 94 % yields, respectively (Scheme 4). The electrochemical behaviors of the two active materials mixed with carbon black (30 wt.%) have been investigated in a carbonatebased liquid electrolyte.…”

Section: Imides Based On π-Conjugated Electrode Active Materialsmentioning

confidence: 99%

Carbonyl‐Based π‐Conjugated Materials: From Synthesis to Applications in Lithium‐Ion Batteries

Oubaha

Melinte

2019

ChemPlusChem

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The constant growth in the global energy demand together with the increasing awareness of clean and sustainable development has strongly pushed scientists to search for metal‐free, low‐cost, environmentally friendly functional energy‐storage systems (ESSs). Among the reported organic electrode materials, carbonyl‐based π‐conjugated compounds show excellent rate capabilities and cycling stabilities and are powerful candidates for the next generation of rechargeable lithium‐ion batteries (LIBs). Benefiting from the molecular structure versatility and design feasibility, the electrochemical properties of organic and polymeric materials can be easily tuned. This Review summarizes recent efforts in the search for carbonyl‐based π‐conjugated electrode materials in LIBs with a focus on the synthetic strategies developed to improve their electrochemical performance. The use of these materials in flexible, all‐organic LIBs is highlighted as a unique direction towards widespread applications of LIBs.

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Carboxylic and sulfonic N-substituted naphthalene diimide salts as highly stable non-polymeric organic electrodes for lithium batteries

Cited by 38 publications

References 25 publications

Analytical Measurements to Elucidate Structural Behavior of 2,5‐Dimethoxy‐1,4‐benzoquinone During Charge and Discharge

Analytical Measurements to Elucidate Structural Behavior of 2,5‐Dimethoxy‐1,4‐benzoquinone During Charge and Discharge

Hierarchical Nanostructured Benzoic Naphthalene Tetracarboxylic Di‐imide Organic Cathode for Lithium Ion Battery

Carbonyl‐Based π‐Conjugated Materials: From Synthesis to Applications in Lithium‐Ion Batteries

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