Carbonylation of Methanol with CO in Presence Potassium Methoxide Catalyst

Hendriyana,; Subagjo,; Susanto, Herri

doi:10.1016/j.proche.2015.12.019

Cited by 4 publications

(1 citation statement)

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“…The chemistry of carbon monoxide is one of the main directions in the production of liquid transportation fuels and valuable chemicals. Fischer-Tropsch synthesis, methanol synthesis, hydroformylation, and carbonylation are the major reactions used for these purposes [1][2][3][4][5][6]. In C 1 chemistry, synthesis gas plays the role of the reactant and also can be the part of the active catalyst complex [7,8].…”

Section: Introductionmentioning

confidence: 99%

Synthesis‐Gas Absorption under Real Process Conditions: Thermodynamic Aspects

et al. 2019

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The solubility of synthesis gas was measured in the temperature range of 100–300 °C and pressure range of 1.0–5.0 MPa in polar (2‐propanol) and nonpolar (n‐dodecane) solvents. Thermodynamic parameters of the absorption, such as the Henry constant, absorption enthalpy, and apparent activation energy of absorption, were calculated on the basis of the obtained results. The phase equilibrium was calculated by using the Soave‐Redlich‐Kwong cubic equation of state, which could be used to predict the optimal process conditions for liquid‐phase Fischer‐Tropsch reactions in different solvents.

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