Abstract:Carbon monoxide, with the use of transition-metal catalysis, has become a valuable C1 building block. 1 Carbonylation is one method of intercepting the palladium intermediates generated by oxidative addition. 2 If the reaction is run under at atmosphere of carbon monoxide, then the palladium intermediate may undergo CO insertion, generating an 1 -acyl complex, before any other reagent (Scheme 4.1). Whether it will do so in useful quantities is a question of kinetics: will the rate of CO insertion be faster tha… Show more
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