“…Driven by the van der Waals interaction, graphene with exceptional electrical [1][2][3], thermal [4][5][6], mechanical [7][8][9] properties yet extreme flexibilities [10,11] is prone of selffolding [12,13] and self-tearing [14], leading to the twodimensional (2D) to three-dimensional (3D) configuration transition and sequential complex spatial structures, such as ribbon [15], foams [16] and polyhedral [17,18], in a load-free and self-assembly [19][20][21] manner. This promises various engineering and potential applications, including straininsensitive sensors [22][23][24], stretchable electronics [25], water desalination [26], thermal transparency and thermoelectric material [27,28], nanomotors [29], heat management systems [30], walking devices [31] and biosensing skin [32].…”