Nanofiltration (NF) technology is attractive in desalting
and concentrating
dyeing wastewater in the textile industry. A highly efficient NF membrane
is critical in reducing the cost of the process. Here, a facile and
reliable approach to prepare an NF membrane for the selective separation
of dye/salt is proposed by surface grafting of 3-aminopropyltriethoxysilane
(APTES) on a fresh polyamide (PA) layer after interfacial polymerization
(IP). A thin layer of APTES with a thickness of ∼64 nm was
found successfully covalently bonded onto the PA surface via esterification
and amidation reactions. The thin-film composite (TFC)-1.0 membrane
grafted with 10% APTES achieved a high water permeance of 44.8 L m–2 h–1 bar–1, which
was 4.7 times higher than that of the control TFC membrane. Interestingly,
the rejection of monovalent salt (NaCl, 11.5%) and divalent salt (Na2SO4, 17.2%) decreased significantly, while the
rejection for different dyes (Congo red, reactive blue-19, Coomassie
blue G-250, and methyl blue) remained over 99.0%. These noticeable
changes in separation performances could be attributed to the large
pore size of the active layer, resulting from the interference of
APTES on the post-cross-linking of a PA network. The poly(ethylene
glycol) (PEG) filtration experiments confirmed that the mean pore
size of the membrane was enlarged significantly from 0.51 to 1.17
nm after surface modification. Finally, the modified membrane showed
good long-term stability and excellent separation efficiencies in
fractionation of a high salinity Congo red/NaCl (0.2/50 g L–1) mixture. Overall, this work provides a practical strategy to prepare
a permeable and selective NF membrane for dye and salt separation
by surface grafting of the nascent PA layer.