To mitigate the microbiologically
influenced corrosion of metallic
components serving in marine environments, an innovative Ag nanoparticle
(AgNP)/NbC nanocomposite coating was synthesized using a double glow
discharge plasma method. The coating was composed of Ag nanoparticles
together with NbC nanocrystals embedded in an amorphous carbon (a-C)
matrix. The incorporation of Ag into the NbC coating played a significant
role in determining both the grain size and crystallographic texture
of the NbC phase, as well as the bonding state of the carbon species
and the surface morphology of the coating. Following immersion in
sulfate-reducing bacteria (SRB)-inoculated artificial seawater, the
planktonic SRB cell count for the AgNPs/NbC nanocomposite coating
was found to be two and three orders of magnitude lower than those
of the Ag-free NbC coating and bare Ti-6Al-4V, respectively. The electrochemical
corrosion behavior of the AgNPs/NbC nanocomposite coating was evaluated
and compared to the Ag-free NbC coating and bare Ti-6Al-4V in SRB-inoculated
artificial seawater by using potentiodynamic polarization and electrochemical
impedance spectroscopy (EIS). The semiconducting properties of the
oxide film grown on the nanocomposite coating were drawn from Mott–Schottky
analysis. The results showed that Ag additions improved the microbiologically
influenced corrosion (MIC) resistance of the NbC coating and led to
the transformation of the electronic structure of the oxide film from
an n-type semiconductor to a p–n heterojunction structure.