Carbon Material with a Highly Ordered Linear-Chain Structure

Flood, P. F.; Babaev, V. G.; Khvostov, V. V.; Novikov, N. D.; Гусева, М. Б.

doi:10.1201/9781420027587.ch11

Cited by 15 publications

(17 citation statements)

References 20 publications

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“…For example, 1D thermal transport seems valuable, as the heat conduction would be directed along the chain [10]. A prospective advance is the ion-assisted condensation of sp 1 -chains, ordered in a hexagonal array with 5 Å distance between 2D-ordered linear-chained carbon (LCC) [12]. Being synthesized from carbon ions and their clusters in the plasma beam, they nevertheless present a material macroscopic in two dimensions.…”

Section: Introductionmentioning

confidence: 99%

Structure and Properties of Chained Carbon: Recent Ab Initio Studies

Бунтов

Zatsepin

Kitayeva

et al. 2019

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Carbon chains or carbyne-like structures represent the next generation of 1D materials whose properties can be tuned by the chain length, doping, and the type of termination. Currently inaccessible technology of the macroscopic carbyne synthesis and characterization makes theoretical work especially valuable. The state of the art methods being applied in the field are density functional theory and molecular dynamics. This paper provides a review of the current state of research on modeling linear carbon structures and related materials. We show that even though the “static” properties of carbon chains (mechanical strength, thermal conduction, band gaps, and phonon spectra) are extensively described, there are only a few simulations of the synthesis processes that constitute the next challenge in 1D research.

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Section: Introductionmentioning

confidence: 99%

Structure and Properties of Chained Carbon: Recent Ab Initio Studies

Бунтов

Zatsepin

Kitayeva

et al. 2019

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“…The spatial configuration of a 2D-ordered linear-chain carbon looks like a two-dimensionally distributed hexagonal set of the parallel carbon chains interconnected by the van der Waals forces. In this case, the distance between the carbon chains is estimated as 5Å [ 27 , 28 ].…”

Section: Features and Synthesis Of The Functionalizing Nanocarriersmentioning

confidence: 99%

Tailoring Vibrational Signature and Functionality of 2D-Ordered Linear-Chain Carbon-Based Nanocarriers for Predictive Performance Enhancement of High-End Energetic Materials

Lukin¹,

Gülseren

2022

Nanomaterials

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A recently proposed, game-changing transformative energetics concept based on predictive synthesis and preprocessing at the nanoscale is considered as a pathway towards the development of the next generation of high-end nanoenergetic materials for future multimode solid propulsion systems and deep-space-capable small satellites. As a new door for the further performance enhancement of transformative energetic materials, we propose the predictive ion-assisted pulse-plasma-driven assembling of the various carbon-based allotropes, used as catalytic nanoadditives, by the 2D-ordered linear-chained carbon-based multicavity nanomatrices serving as functionalizing nanocarriers of multiple heteroatom clusters. The vacant functional nanocavities of the nanomatrices available for heteroatom doping, including various catalytic nanoagents, promote heat transfer enhancement within the reaction zones. We propose the innovative concept of fine-tuning the vibrational signatures, functionalities and nanoarchitectures of the mentioned nanocarriers by using the surface acoustic waves-assisted micro/nanomanipulation by the pulse-plasma growth zone combined with the data-driven carbon nanomaterials genome approach, which is a deep materials informatics-based toolkit belonging to the fourth scientific paradigm. For the predictive manipulation by the micro- and mesoscale, and the spatial distribution of the induction and energy release domains in the reaction zones, we propose the activation of the functionalizing nanocarriers, assembled by the heteroatom clusters, through the earlier proposed plasma-acoustic coupling-based technique, as well as by the Teslaphoresis force field, thus inducing the directed self-assembly of the mentioned nanocarbon-based additives and nanocarriers.

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“…Relatively recently, a method was found to compensate for the above disadvantages by using the technology of ion-plasma growing of stable carbine-like nanostructures in the composition of multi-cavity nano-matrixes, [10]. Such nano-sized carbon structures obtained the name as two-dimensionally ordered linear-chain carbon, which is a two-dimensionally packed hexagonal array of carbon chains held by van der Waals forces at a distance of about 5 angstroms.…”

Section: Predictive Functionalization Of the Carbon-based Nanostructumentioning

confidence: 99%

Energetic Materials Performance Enhancement Through Predictive Programming the Spatial Structure and Physics-Chemical Properties of the Functionalized Carbon-Based Nano-Sized Additive<strong> </strong>

Lukin¹

2021

Preprint

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A new generation of nano-technologies is expanding solid propulsion capabilities and increasing their relevance for versatile and manoeuvrable micro-satellites with safe high-performance propulsion. We propose the innovative concept, connected with application of new synergistic effect of the energetic materials performance enhancement and reaction zones programming for the next generation small satellite multimode solid propulsion system. The main idea of suggested concept is manipulating by the self-organized wave patterns excitation phenomenon, by the properties of the energetic materials reaction zones and by localization of the energy release areas. This synergistic effect can be provided through application of the functionalized carbon-based nanostructured metamaterials as a nano-additives along with simultaneous manipulating by their properties through the electrostatic field. Mentioned effect will be controlled through predictive programming both by the spatial structure and physics-chemical properties of the functionalized carbon-based nano-additives and through the electromagnetic control of the self-organized wave pattern excitation and micro- and nano- scale oscillatory networks in the energetic material reaction zones. Suggested new concept makes it possible to increase the energetic material regression rate and increase the thrust of the solid propulsion system with minimal additional energy consumption.

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Carbon Material with a Highly Ordered Linear-Chain Structure

Cited by 15 publications

References 20 publications

Structure and Properties of Chained Carbon: Recent Ab Initio Studies

Structure and Properties of Chained Carbon: Recent Ab Initio Studies

Tailoring Vibrational Signature and Functionality of 2D-Ordered Linear-Chain Carbon-Based Nanocarriers for Predictive Performance Enhancement of High-End Energetic Materials

Energetic Materials Performance Enhancement Through Predictive Programming the Spatial Structure and Physics-Chemical Properties of the Functionalized Carbon-Based Nano-Sized Additive<strong> </strong>

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