1976
DOI: 10.1139/v76-364
|View full text |Cite
|
Sign up to set email alerts
|

Carbon kinetic isotope effects in the oxidation of oxalate by permanganate in aqueous solutions of sulfuric acid

Abstract: Fractionation of the carbon isotopes occurs during the oxidation of oxalate by permanganate in aqueous sulfuric acid. The isotope effect, expressed as k12/k13, rises from near unity in the very early stages of the reaction, to reach a value of 1.037 ± 0.001 after completion of the induction period. Addition of fluoride prolongs the induction period, and reduces the isotope effect to values near 1.000. These observations are consistent with there being two essentially independent paths for formation of carbon d… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

1976
1976
2016
2016

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
references
References 5 publications
(6 reference statements)
0
0
0
Order By: Relevance