Carbon-integrated semiconductor photocatalysts for removal of volatile organic compounds in indoor environments

Ahmad, Adnan; Ali, Mumtaz; Mohammed, Mohammed Elimam Ahamed; Al‐Ghamdi, Ahmed A.; Park, Jae-Woo; Algarni, H.; Anwer, Hassan

doi:10.1016/j.cej.2022.139436

Cited by 40 publications

(9 citation statements)

References 212 publications

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“…Here, we summarize the important research in the oxidation of organic compounds by g-CNs. Catalytic processes by metal-free g-CNs can be carried out by thermal or photocatalysis methodologies [ 111 ]. Thermal oxidation usually employs O 2 or H 2 O 2 as an oxidant in the absence of light.…”

Section: Prominent Catalysis Using Carbon Nitridementioning

confidence: 99%

Organocatalysis with carbon nitrides

Ruban

Ramadass

Singh

et al. 2023

Science and Technology of Advanced Materials

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Carbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis. This is largely possible due to their low cost, exceptional thermal and chemical stability, non-toxicity, ease of functionalization, porosity development, etc. Especially, the carbon nitrides with increased porosity and nitrogen contents are more versatile than their bulk counterparts for catalysis. These N-rich carbon nitrides are discussed in the earlier parts of the review. Later, the review highlights the role of such carbon nitride materials for the various organic catalytic reactions including Knoevenagel condensation, oxidation, hydrogenation, esterification, transesterification, cycloaddition, and hydrolysis. The recently emerging concepts in carbon nitride-based organocatalysis have been given special attention. In each of the sections, the structure–property relationship of the materials was discussed and related to their catalysis action. Relevant comparisons with other catalytic materials are also discussed to realize their real potential value. The perspective, challenges, and future directions are also discussed. The overall objective of this review is to provide up-to-date information on new developments in carbon nitride-based organic catalysis reactions that could see them rising as prominent catalytic materials in the future.

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Section: Prominent Catalysis Using Carbon Nitridementioning

confidence: 99%

Organocatalysis with carbon nitrides

Ruban

Ramadass

Singh

et al. 2023

Science and Technology of Advanced Materials

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“…Further, Ahmad et al [ 164 ] discussed carbon‐integrated SC photocatalysts to remove the volatile organic compounds from indoor air. Carbon‐based materials include activated carbon, rGO, MOF, MXene, carbon QDs, g–C 3 N 4 , carbon nano‐tubes, etc.…”

Section: Applications Of Hybrid Sc Photocatalyst Nanomaterialsmentioning

confidence: 99%

“…Pristine TiO 2 showed negligible performance, while enhanced activity with Bi NPs under 500 nm of visible light illumination to remove NO from the air. [163] Further, Ahmad et al [164] discussed carbon-integrated SC photocatalysts to remove the volatile organic compounds from indoor air. Carbon-based materials include activated carbon, rGO, Reprinted with permission.…”

Section: Air Purificationmentioning

confidence: 99%

Hybrid Semiconductor Photocatalyst Nanomaterials for Energy and Environmental Applications: Fundamentals, Designing, and Prospects

Mishra

Devi

Siwal

et al. 2023

Advanced Sustainable Systems

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The degradation of fossil fuel and worse environmental conditions leads to the emergence of hybrid semiconductor (SC) nanomaterials as photocatalysts. Hybrid SCs have interesting physical, mechanical, optical, chemical, and electronic characteristics. Due to these properties’ absorption of light and transfer of charge takes place frequently and hence act as multifunctional surface. These materials should be attributed to their optical and electrical properties and act as multifunctional surfaces in energy production, fuel generation, environmental remediation, sensing, etc. When SCs combine with noble, non‐noble metal, metal oxide, and some carbon‐based materials, they explore wide applications in various fields. Photocatalysis is an effective and sustainable technology to reduce or fix energy concerns and environmental corrosion problems. By going through the extensive literature review, few topics are focused on designing and working mechanisms of hybrid materials. In this way, the present review article explains the properties, surface‐interface engineering, design, and applications (energy and environmental) of hybrid nanomaterials, emphasizing their photocatalytic nature. Additionally, the appealing directions, scientific challenges, and the reasons behind the poor stability of Hybrid SC photocatalyst nanomaterials for energy and environmental applications are discussed. Finally, the concluding remarks and the current challenges with future prospects in this domain are highlighted.

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“…In addition, solardriven degradation of pollutants (such as volatile organic compounds, antibiotics and organic dyes) is a powerful technology to solve the problem of environmental pollution. [26][27][28][29][30][31] Since the successful application of TiO 2 in photocatalytic water splitting, 32 a large number of inorganic photocatalysts have been explored, such as oxides (NaTaO 3 , ZnO, and SrTiO 3 ), [33][34][35] suldes (In 2 S 3 and ZnIn 2 S 4 ) [36][37][38] and oxynitrides (Ta 3 N 5 , LaTiO 2 N, and BaTaO 2 N). [39][40][41] Although a series of advances have been achieved in photocatalysis, they usually exhibit low quantum efficiency due to rapid carrier recombination.…”

Section: Zebo Fangmentioning

confidence: 99%

“…In addition, solar-driven degradation of pollutants (such as volatile organic compounds, antibiotics and organic dyes) is a powerful technology to solve the problem of environmental pollution. 26–31…”

Section: Introductionmentioning

confidence: 99%