Carbon-Fuelled Solid Oxide Cells for Military Applications

Abstract

We are evaluating the suitability of solid oxide cells for efficient power generation from carbons delivered as solids to the anode space in order to satisfy the requirements of military applications such as waste-to-energy and portable power. Ample evidence in the literature testifies to the feasibility of this concept. In order to de-risk a portable battery system based on this concept, consideration is given in this paper to the anode type, gasification rate of carbons, heat and mass transfer within the cell and the control of a complete system.A palladium-based anode is preferred for operation of a cell with carbon adjacent to the anode since the electrical performance is higher and it is more resistant to oxidation under fuel starved conditions than traditional nickel anodes. There is ample experimental evidence that carbon can gasify in CO 2 at sufficient rate to support operation of a battery system based on cells bearing these anodes. In fact, cell modelling suggests it is the activity of the anode that is limiting. There are significant heat and mass transfer effects within the components of the cell, but these may not prevent the achievement of sufficient electrical performance to enable a portable system. System modelling suggests such a system at the 150 W scale and equipped with enough carbon for 12 hour operation could be 48% efficient.

The Structural Optimization of Ceramic Fuel Cells

“…The early stage of solid oxide development is closely associated with particular activities of prominent scientists such as H. Davy (1802), who probably was the first who formulated the very idea of fuel cell, Michael Faraday (1833) with his well-known research on electrolytes, and Jean-Mathee Gaugain (1853), who discovered galvanic solid electrolyte gas cells. The need in solid electrolytes has grown in the late 19 th century when Pavlo Jablochkoff (1877), Wilhelm Ostwald (1894) and others have been developing fuel cell electrodes that could withstand aggressive liquid electrolytes such as molten alkali carbonates in order to realize the idea "Electricity Directly from Coal" that was then popular, and that, by the way, begun to be interesting now again [5].…”