Carbon dots from eco-friendly precursors for optical sensing application: an up-to-date review

Abstract

Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability, low cytotoxicity, remarkable aqueous solubility, favourable biocompatibility, low risk to environment and great flexibility in surface modification. Fluorescent CDs that can selectively respond to specific inorganic/organic target molecules in environmental and biological samples are of prime significance amongst the new generation intelligent sensors due to the critical involvement of different ions/molecular species in not only human health, but also in environment processes. In this context, preparation of CDs from bioprecursors has immense significance due to the involvement of green principles, inexpensive, clean, nontoxic, easily accessible, renewable and large-scale production can be realized. This article aims at exploring different types of green raw materials including plant biomass, animal products, food items and waste materials as carbon sources for the synthesis of both undoped and doped CDs. The emphasis is given on different synthetic approaches adopted for improving the quantum yield without any chemical modification, the characterization techniques, mechanistic origin of photoluminescence and fluorescence response mechanisms involved in the sensing action towards various analytes. The significant benefits and limitations of CDs obtained from eco-friendly precursors through green approaches are summarized. Various challenges and the future prospects of these carbonaceous nanomaterials as sensors are also discussed. Graphical abstract

Hydrothermal Synthesis of Carbon Quantum Dots: An Updated Review

“…The close spacing between emitting centers on the particle surface of a highly concentrated CQD solution may be causing non-radiative recombination of charge carriers. In contrast, lower non-radiative relaxation and higher light yield are shown by low concentration of CQDs [110]. The inductive and conserving effects of decreasing concentration can lead to a blueshifted emission wavelength [111].…”

Biomass-derived carbon dots as a nanoswitch, logic gate operation, and electrochemical sensor for flavonoids

“…The utilization of green sources has several benefits because they are readily available, inexpensive, somewhat clean in their reactions, and non-toxic. 35 The same CDs acted as a triple mode detector of analytes, which makes this work outstanding.…”

An overview on animal/human biomass-derived carbon dots for optical sensing and bioimaging applications

“…7,28,29 Besides the conventional chemical precursors, there has been extensive research on the synthesis, properties, and applications of natural biomass/waste source-derived CDs as evidenced by the large number of review articles. 30–55…”