Carbon Dioxide Adsorption by Calcium Zirconate at Higher Temperature

Abstract

<p>The CO₂ adsorption by<strong> </strong>calcium zirconate was explored at pre- and post- combustion temperature condition. The several samples of the calcium zirconate were prepared by different methods such as sol-gel, solid-solid fusion, template and micro-emulsion. The samples of the calcium zirconate were characterized by measurement of surface area, alkalinity/acidity, and recording the XRD patterns and SEM images. The CO₂ adsorptions by samples of the calcium zirconate were studied in the temperature range 100 to 850 ^oC and the CO₂ adsorptions were observed in the ranges of 6.88 to 40.6 wt % at 600 ⁰C and 8 to 16.82 wt% at in between the temperatures 200 to 300 ^oC. The effect of Ca/Zr mol ratio in the samples of the calcium zirconate on the CO₂adsorption and alkalinity were discussed. The adsorbed moisture by the samples of the calcium zirconate was found to be useful for the CO₂adsorption. The promoted the samples of the calcium zirconate by K⁺, Na⁺, Rb⁺, Cs⁺, Ag⁺ and La³⁺ showed the increased CO₂ adsorption. The exposure time of CO₂ on the samples of the calcium zirconate showed the increased CO₂ adsorption. The samples of the calcium zirconate were found to be regenerable and reusable several times for the adsorption of CO₂ for at the post- and pre-combustion temperature condition. Copyright © 2012 by BCREC Undip. All rights reserved</p><p><em>Received: 23rd June 2012, Revised: 28th August 2012, Accepted: 30th August 2012</em></p><p><strong>[How to Cite</strong>: K. B. Kale, R. Y. Raskar, V. H. Rane and A. G. Gaikwad (2012). Carbon Dioxide Adsorption by Calcium Zirconate at Higher Temperature. <em>Bulletin of Chemical Reaction Engineering & Catalysis</em>, 7 (2): 124-136. doi:10.9767/bcrec.7.2.3686.124-136]</p><p><strong> </strong><strong>[How to Link / DOI</strong>: <a href="http://dx.doi.org/10.9767/bcrec.7.2.3686.124-136">http://dx.doi.org/10.9767/bcrec.7.2.3686.124-136</a> ]</p><p><a href="http://www.scopus.com/inward/citedby.url?scp=84872465489&partnerID=65&md5=7cb5e3107671a44facb3939851f002a0" target="_blank"><img src="http://searchapi.scopus.com/citedby?&citedbycount=http://be-layer7-prod/content/abstract/citation-count?doi=10.9767/bcrec.7.2.3686.124-136&authToken=sat_265808957B530BD3E2947A171BBCB8E8900FFBC4380C35F86092CB00B8F943EFEB5F976632665CD2DAC80B0E7180E764738B5D2614C71C2AD0AA02E2DA68DFA48382F2F28D362F09F1EEBB27B639F86EA00C096C0F0A785ED77B860D868A02C24A8C6F6D4B9DCC3E075616AE50AB08C899F9D5C4FE3298585E29FEE0A4329ABDC424B1547DB7D7AB294D903A57510DDA1A0F679C4C96784DB37F3EBF4055F46C2524C06DF23A6AD289B642B1287F77E67EE3F68E85562F30&ipAddress=182.255.2.13&contentAPIKey=9cf02f45d6c541820cab5d2cd870c4f6&authTokenStatusCode=200" border="0" alt="" /></a> | <a class="noDeco" href="http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84872465489" target="_blank">View in <img style="vertical-align: ...