Carbon‐Coated MOF‐Derived Porous SnPS3 Core–Shell Structure as Superior Anode for Sodium‐Ion Batteries
Ming Yue,
Longsheng Zhong,
Yanzhe Sheng
et al.
Abstract:Metal thiophosphites have recently emerged as a hot electrode material system for sodium‐ion batteries because of their large theoretical capacity. Nevertheless, the sluggish electrochemical reaction kinetics and drastic volume expansion induced by the low conductivity and inherent conversion‐alloying reaction mechanism, require urgent resolution. Herein, a distinctive porous core–shell structure, denoted as SnPS3@C, is controllably synthesized by synchronously phosphor‐sulfurizing resorcinol‐formaldehyde‐coat… Show more
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