1987
DOI: 10.1002/aic.690330109
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Carbochlorination of metal oxides with phosgene

Abstract: Kinetics of the carbochlorination with phosgene of an alumina-silica material are reported for a temperature range of 723 to 1,023 K and a phosgene partial pressure range of 4 to 90 kPa. The oxides react in a constant ratio over most of the conversion range and the grain model accurately predicts conversion as a function of time.

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Cited by 8 publications
(1 citation statement)
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“…The most often used chlorinating agents for that purpose are: chlorine (Uchumira et al, 1963;Rosner and Allendorf, 1965;Nair et al, 1987;SzCpvolgyi et al, 1988); chlorine in the presence of carbon (Saeki et al, 1965a(Saeki et al, , 1965bFuwa et al, 1978;Biceroglu and Gauvin, 1980; Barin and Shuler, 1980;Nolasco, 1983), a mixture of chlorine and carbon monoxide (Akimoto et al, *Author to whom correspondence should be addressed. Milne, 1976;Alder, 1977;Muller et al, 1979; Rivarola et al, 1981;Rub et al, 1988;phosgene (SzCpvolgyi et al, 1988;Adelman and Burnet, 1987) and carbon tetrachloride (Podoinikova and Chernyi, 1963;Papa et al, 1977;Bertdi et al, 1980;Rivarola et al, 1982;Ojeda et al, 1983;Ruiz and Rivarola, 1983;Blumenthal and Hauthal, 1987;Herrick et al, 1988;.…”
mentioning
confidence: 99%
“…The most often used chlorinating agents for that purpose are: chlorine (Uchumira et al, 1963;Rosner and Allendorf, 1965;Nair et al, 1987;SzCpvolgyi et al, 1988); chlorine in the presence of carbon (Saeki et al, 1965a(Saeki et al, , 1965bFuwa et al, 1978;Biceroglu and Gauvin, 1980; Barin and Shuler, 1980;Nolasco, 1983), a mixture of chlorine and carbon monoxide (Akimoto et al, *Author to whom correspondence should be addressed. Milne, 1976;Alder, 1977;Muller et al, 1979; Rivarola et al, 1981;Rub et al, 1988;phosgene (SzCpvolgyi et al, 1988;Adelman and Burnet, 1987) and carbon tetrachloride (Podoinikova and Chernyi, 1963;Papa et al, 1977;Bertdi et al, 1980;Rivarola et al, 1982;Ojeda et al, 1983;Ruiz and Rivarola, 1983;Blumenthal and Hauthal, 1987;Herrick et al, 1988;.…”
mentioning
confidence: 99%