Can Rare Earth Elements Be Considered as Markers of the Varietal and Geographical Origin of Wines?

Темердашев, З. А.; Bolshov, M.A.; Abakumov, A. G.; Khalafyan, А. А.; Kaunova, A. A.; Vasilyev, Alexander; Shelud'ko, Olga Nikolaevna; Ramazanov, A. Sh.

doi:10.3390/molecules28114319

Cited by 3 publications

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“…Strong correlations were observed in the berry-wine chain; the correlation coefficients for all territories are close to 1 (R 2 > 0.996), and a positive sign means that the higher the metal concentration in the berry, the higher its content in the wine. This statement is true, provided that technological processes do not interfere with the processing of wine materials in such a way that they significantly alter its "elemental composition" [61][62][63].…”

Section: The Correlation Between the Elemental Composition Of Soil Gr...mentioning

confidence: 99%

The Influence of the Soil Profile on the Formation of the Elemental Image of Grapes and Wine of the Cabernet Sauvignon Variety

Temerdashev,

Abakumov,

Khalafyan

et al. 2024

Molecules

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The features for assessing the authenticity of wines by region of origin are studied, based on the relationship between the mineral composition of the wine, the grapes, and the soil profile (0 to 160 cm) from the place of growth of Cabernet Sauvignon grapes. Soil, grape, and wine samples were taken from the territories of six vineyards in the Anapa district of Krasnodar Territory, Russia. Using the methods of ICP-OES, thermal, and X-ray phase analysis, the soils were differentiated into three groups, differing in mineralogical and mineral compositions. The soil samples of the first group contained up to 31% quartz, the second group up to 25% quartz and 19% mixed calcite, and the third group up to 32% calcite and 15% quartz. The formation of the elemental image of the grapes was studied, taking into account the total content and mobile forms of metals in the soil. The territorial proximity of the vineyards did not affect the extraction of elements from the soil into the grape berry, and the migration of metals for each territory was selective. According to the values of the biological absorption coefficient, the degree of transition of metals from the soil to a berry was estimated. For K, Ti, Zn, Rb, Cu, and Fe in all berries, the coefficient was higher than 1.00, which means that the berry extracts contained not only mobile-form, but also difficult-to-dissolve metal compounds. The migration of macro-components from the soil to the berry was low, and amounted to 6–7% for Ca, 0.8–3.0% for Na, and 25–70% for Mg of the concentration of their mobile forms. For all territories, the maximum correlation between metal concentrations in grapes and soil was observed for samples from a depth of 0–40 cm. The discriminant model based on concentrations of Rb, Al, K, Sr, Co, Na, Pb, Ca, and Ni showed the formation of clusters in the territories of vineyard cultivation. The developed model allow the problems of identifying wines by region to be solved with high accuracy, using their elemental image.

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Section: The Correlation Between the Elemental Composition Of Soil Gr...mentioning

confidence: 99%