Citizen science has been recognized for its potential to contribute to the UN Sustainable Development Goals in multiple ways (e.g., for defining and monitoring indicators, data production, etc.). In this paper, we focus on Extreme Citizen Science, which includes a set of situated, bottom-up practices, used for environmental monitoring purposes and for recording local indigenous knowledge, mainly in the Global South. Here we present and discuss the human-centered approach that the implementation of extreme citizen science requires, and we identify and discuss the challenges that we face as well as the opportunities that extreme citizen science initiatives can create for contributing to the Sustainable Development Goals.