Calorimetric studies of binary systems of 1,3,5-trinitrobenzene with naphthalene, anthracene and carbazole. I. Phase transitions and heat capacities of the pure components and charge-transfer complexes

The design, construction, and testing of a new Knudsen effusion apparatus

“…For anthracene, the mean value D g cr C p;m ¼ À27 J Á mol À1 Á K À1 was estimated from the value C p;m (cr, T = 298.15 K) = 211.7 J AE mol À1 AE K À1 , presented by Radomska and Radomski [12] and from the value C p;m (g, T = 298.15 K) = 185.0 J AE mol À1 AE K À1 , presented by Kudchaker et al [13]. For phenanthrene, the mean value D g cr C p;m ¼ À34 J Á mol À1 Á K À1 was estimated from the value C p;m (cr, T = 298.15 K) = 220.3 J AE mol À1 AE K À1 , presented by Steele et al [14] and from the value C p;m (g, T = 298.15 K) = 186.8 J AE mol À1 AE K À1 , presented by Kudchaker et al [13].…”

New Knudsen effusion apparatus with simultaneous gravimetric and quartz crystal microbalance mass loss detection

“…The applied methodology was based on a temperature step effusion procedure that allows the determination of the overall effective mass sensitivity coefficient, W, derived from the experimental gravimetric cell mass loss (equation (10)). The vapour pressure is then calculated from @f @t corr for each defined isothermal step, using equation (11).…”

Solid‐Liquid Equilibrium of Tröger's Base Enantiomers in Ethanol: Experiments and Modelling

“…The solid racemic compound is labelled with subscript r. For the equilibrium condition at temperature T between pure crystals of one enantiomer and a liquid phase constituted of the same enantiomer and of either the other enantiomer or the solvent or both, the SchrˆderÀvan Laar equation (Eqn. 1) must be fulfilled under rather standard thermodynamic assumptions [3] [21] [22]:…”