Calibration of absorption coefficients of liquid solutions for measuring liquid film thickness by absorptiometry

Abstract

Infrared absorptiometry is a widely used non-intrusive method for measuring the thickness of liquid films. The accuracy of that measurement depends crucially on having high-accuracy data of the absorption coefficient of the laser light used, which is, however, not easily available, especially for the wavelength range where the absorption is strong. Here we propose a method to calibrate the absorption coefficients in such cases. By measuring the light intensity reduction while scanning through a liquid film formed in a wedge, whose angle can be adjusted and determined a priori from interferometry, the absorption coefficient of the liquid can be accurately obtained without the need to create a flat liquid film with exact known thickness. The method is verified by calibrating the absorption coefficient of pure water at an infrared wavelength and the result agrees very well with the values found in the literature. As a demonstration of the application of the method, the absorption coefficients of soap solutions with different compositions were calibrated and used to measure the thicknesses of draining soap films. The results from the absorptiometry are in good agreement with the film thickness measured simultaneously from interferometry.