For κ = 0, 1, −1, let M κ be the three dimensional space form of curvature κ, that is, R 3 , S 3 and hyperbolic 3-space H 3 . Let G κ be the manifold of all oriented (unparametrized) complete geodesics of M κ , i.e., G 0 and G −1 consist of oriented lines and G 1 of oriented great circles.Given a strictly convex surface S of M κ , we define an outer billiard map B κ on G κ . The billiard table is the set of all oriented geodesics not intersecting S, whose boundary can be naturally identified with the unit tangent bundle of S. We show that B κ is a diffeomorphism under the stronger condition that S is quadratically convex.We prove that B 1 and B −1 arise in the same manner as Tabachnikov's original construction of the higher dimensional outer billiard on standard symplectic space R 2n , ω . For that, of the two canonical Kähler structures that each of the manifolds G 1 and G −1 admits, we consider the one induced by the Killing form of Iso (M κ ). We prove that B 1 and B −1 are symplectomorphisms with respect to the corresponding fundamental symplectic forms. Also, we discuss a notion of holonomy for periodic points of B −1 .