Cadmium(<scp>ii</scp>) coordination polymers based on substituted malonic acid: synthesis, characterization and photoluminescence properties

Déniz, Mariadel; Pasán, Jorge; Rasines, Beatriz; Lorenzo‐Luis, Pablo; Lahoz, F.; Vera-Gonzales, Corina; Julve, Miguel; Ruíz-Pérez, Catalina

doi:10.1039/c7qi00212b

Cited by 11 publications

(2 citation statements)

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“…18 The d 10 metal centre has no electronic preference for any particular coordination geometry so may adopt a wide variety of coordination modes, allowing for the synthesis of diverse structures. [19][20][21] Synthesis and characterisation of 1-6…”

Section: Reactions Between H 3 Cmai and Cadmium(ii) Saltsmentioning

confidence: 99%

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

et al. 2022

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Section: Reactions Between H 3 Cmai and Cadmium(ii) Saltsmentioning

confidence: 99%

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

et al. 2022

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“…The interaction between {Cu(mal) 2 } 2– and Cd 2+ cations having a larger radius leads to the formation of the 3D polymeric structure of the Cu‐Cd heterometallic compound ,. However, the simultaneous variation of both the 3d‐center in the bis‐malonate fragment and the substituent in the malonate anion has not been studied in such systems, although these factors can have a significant effect on the structure of the compounds obtained …”

Section: Introductionmentioning

confidence: 99%

Binding Features of {M(3d)(cbdc)₂} Blocks (M(3d)=V^IVO, Cu^II; cbdc^2–=Dianion of Cyclobutane‐1,1‐Dicarboxylic Acid) in Formation of Heterometallic Structures with d‐Metal Cations

et al. 2018

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Compounds containing bis-chelate dianionic blocks {M(3d) (cbdc) 2 } 2-(M(3d) = V IV O, Cu II ) with cations VO 2 + and Cu 2 + chelated by two anions of dicarboxylic acid have been prepared as crystals when aqueous solutions of vanadyl sulfate VOSO 4 ⋅3H 2 O or copper sulfate CuSO 4 ⋅5H 2 O have been allowed to react with sulfates of d-metals (Mn II , Co II , Ni II , Zn II , and Cd II ) and barium salt of cyclobutane-1,1-dicarboxylic acid (H 2 cbdc = C 4 H 6 (CO 2 H) 2 ) in the 1:1:2 ratio. The nature of the M(3d) metal center has been found to influence on the structure of the heterometallic compounds formed. 1D polymers [M(VO) (cbdc) 2 (EtOH) 2 (H 2 O) 3 ] n (M = Mn (1), Co (2), Ni (3)), molecular dinuclear complex [Zn(VO)(cbdc) 2 (H 2 O) 5 ]⋅H 2 O (4), and 1D polymer {[Cd(VO)(cbdc) 2 (H 2 O) 5 ]⋅H 2 O} n (5) are formed when M(3d) = V IV O, whereas in the case of the bis-chelate block with the Cu II atom, ionic compounds [M(H 2 O) 6 ][Cu(cbdc) 2 (H 2 O)] (M = Mn (6), Co (7), Ni (8), Zn (9)) and 2D polymer {[CdCu(cbdc) 2 (H 2 O) 2 ] ⋅2H 2 O} n have been synthesized. The isolation of paramagnetic centers in compounds 1-10 is confirmed by magnetic measurements and EPR spectroscopy.

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Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

Matiukhina,

Chistyakov,

Zorina-Tikhonova

et al. 2023

Monatsh Chem

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Cadmium(ii) coordination polymers based on substituted malonic acid: synthesis, characterization and photoluminescence properties

Abstract: The influence of the chain length on the topology and luminescence of four new cadmium(ii) R-malonate coordination polymers is analysed herein.

Cited by 11 publications

References 46 publications

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

Binding Features of {M(3d)(cbdc)₂} Blocks (M(3d)=V^IVO, Cu^II; cbdc^2–=Dianion of Cyclobutane‐1,1‐Dicarboxylic Acid) in Formation of Heterometallic Structures with d‐Metal Cations

Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

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Cadmium(ii) coordination polymers based on substituted malonic acid: synthesis, characterization and photoluminescence properties

Abstract: The influence of the chain length on the topology and luminescence of four new cadmium(ii) R-malonate coordination polymers is analysed herein.

Cited by 11 publications

References 46 publications

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

Synthesis, structures and properties of metal–organic frameworks prepared using a semi-rigid tricarboxylate linker

Binding Features of {M(3d)(cbdc)2} Blocks (M(3d)=VIVO, CuII; cbdc2–=Dianion of Cyclobutane‐1,1‐Dicarboxylic Acid) in Formation of Heterometallic Structures with d‐Metal Cations

Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

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Product

Resources

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Binding Features of {M(3d)(cbdc)₂} Blocks (M(3d)=V^IVO, Cu^II; cbdc^2–=Dianion of Cyclobutane‐1,1‐Dicarboxylic Acid) in Formation of Heterometallic Structures with d‐Metal Cations