2022
DOI: 10.1016/j.jhazmat.2021.126807
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Cadmium removal by FeOOH nanoparticles accommodated in biochar: Effect of the negatively charged functional groups in host

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Cited by 26 publications
(5 citation statements)
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“…The AT skeleton's surface is characterized by a deciency of active sites, potentially contributing to a-FeOOH agglomeration. It is also conceivable that the high surface energy of a-FeOOH triggers internal self-agglomeration, 20,21 Fig. 2d showed the SEM morphology of the ATCh40-Fe 2 O 3 skeleton, demonstrating evident agglomeration of Fe 2 O 3 particles on the surface of ATCh40 skeletons.…”
Section: Morphology Studiesmentioning
confidence: 99%
“…The AT skeleton's surface is characterized by a deciency of active sites, potentially contributing to a-FeOOH agglomeration. It is also conceivable that the high surface energy of a-FeOOH triggers internal self-agglomeration, 20,21 Fig. 2d showed the SEM morphology of the ATCh40-Fe 2 O 3 skeleton, demonstrating evident agglomeration of Fe 2 O 3 particles on the surface of ATCh40 skeletons.…”
Section: Morphology Studiesmentioning
confidence: 99%
“…When the PO 4 3À concentration increases, the ionic strength in the solution increases and the thickness of the FeOOH@ZnO/HZ surface double electric layer becomes thinner. The increased anion neutralizes the cationic charge adsorbed on the surface of FeOOH@ZnO/HZ, facilitating the proximity and chemical reaction of S 2À and PO 4 3À with FeOOH@ZnO/HZ (Wu et al 2010;Wan et al 2022). Therefore, the higher the initial concentration of coexisting PO 4 3À ions induced a higher equilibrium adsorption rate of S 2À .…”
Section: Effect Of Po 4 3àmentioning
confidence: 99%
“…Wan et al used different concentrations of HNO 3 (27,41,54, and 68% in mass) to modify biochar and enhance the content of carboxyl and hydroxyl groups. 18 Similarly, Wang et al employed highly oxidizing and toxic chemicals (H 2 O 2 and 3-mercaptopropyl trimethoxy-silane) to modify biochar and improve the efficiency of heavy-metal adsorption. 19 Enhancing the removal of heavy metals via the surface chemical modification of carbon materials becomes difficult owing to their inert surface properties.…”
Section: Introductionmentioning
confidence: 99%
“…To address this issue, surface chemical modification approaches have been used to improve the properties of carbon materials. , However, the AC surface produced via high-temperature pyrolysis lacks hydroxyl and other active groups, thereby necessitating the use of chemical reagents, e.g., corrosive agents, oxidizing agents, and toxic substances, during the modification procedure. Wan et al used different concentrations of HNO 3 (27, 41, 54, and 68% in mass) to modify biochar and enhance the content of carboxyl and hydroxyl groups . Similarly, Wang et al employed highly oxidizing and toxic chemicals (H 2 O 2 and 3-mercaptopropyl trimethoxy-silane) to modify biochar and improve the efficiency of heavy-metal adsorption .…”
Section: Introductionmentioning
confidence: 99%