Cadmium and Mercury

Time-Dependent Photoluminescence Spectroscopy as a Tool to Measure the Ligand Exchange Kinetics on a Quantum Dot Surface

“…Further, it is clear from Figure 4a that amines are rapidly exchanged by thiols, which can be ascribed to the weaker bond strength of amines to Cd sites 41 and faster kinetics due to the relatively small surface area occupied by HDA as compared to TOP or TOPO. Addition of a 100-fold excess of amines initially causes the replacement of both TOPO and TOP by HDA during the 3 day equilibration period.…”

Hydrothermal Studies in the System Hg/Se/Te/O: The First TeIV/SeVI Oxocompounds Hg3SeTe2O10 and Hg3SeTe4O14, and the Mixed‐valent Hg5Se2O8

“…Mercury has a crystal chemistry unique among the elements [33] and shows a strong preference for coordination number of two, resulting in a linear coordination for Hg I [26] see Table 4 [1][2][3][4] The next nearest oxygen atoms are about 2.70 Å away for both Te IV atoms and do not contribute to the first coordination sphere. [1] In comparison with the less 66 Å).…”

Syntheses of bis(organomercury)1,3-dithiole-2-thione-4,5-dithiolates and related compounds: Crystal structure of bis(phenylmercury)1,3-dithiole-2-one-4,5-dithiolate

“…''T'' shaped geometries have been reported for various mercury compounds [62]. As generally found for mercury compounds having ''T'' shaped geometries, the bond to the atom not involved in the near linear X-Hg-Y bond angle is longer than a normal single bond, as illustrated by the Hg1-S2 and Hg2-O1 bond lengths of 2.9315 (12) Table 3 Geometric parameters and symmetry operations for hydrogen bond and intermolecular interactions (Å,°).…”

“…5b. The Hg-C bond lengths, 2.067(5) and 2.078(5) Å, are in the regions normally found for organomercury compounds [62].…”