(Ca, Eu, Yb)<sub>23</sub>Cu<sub>7</sub>Mg<sub>4</sub> as a Step towards the Structural Generalization of Rare Earth-Rich Intermetallics
Pavlo Solokha,
Riccardo Freccero,
Serena De Negri
Abstract:The R23Cu7Mg4 (R = Ca, Eu) intermetallics, studied by single crystal X-ray diffraction, were found to be isostructural with the Yb23Cu7Mg4 prototype (hP68, k4h2fca, space group P63/mmc), forming a small group inside the bigger 23:7:4 family, otherwise adopting the hP68-Pr23Ir7Mg4 crystal structure. The observed structural peculiarity is connected with the divalent character of the R component and with a noticeable volume contraction, resulting in a clear clustering of title compounds inside the whole 23:7:4 fa… Show more
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