[{(C5Me5)2Nb}2PdTe4], a heterometallic palladium telluride cluster with a planar PdTe4 fragment

Kubicki, Marek M.; Schwarz, Patrick; Meier, W.; Wächter, Joachim; Zabel, Manfred

doi:10.1016/j.jorganchem.2007.05.047

Cited by 6 publications

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References 14 publications

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“…70 A heterometallic Pd telluride cluster [{Cp* 2 Nb} 2 PdTe 4 ] with a planar PdTe 4 fragment has also been reported. 71 The reaction of MesPQC(Ph)(py) with [Pd(cod)Cl 2 ] (and the analogous Pt complex) affords a PN-chelate complex [Pd{MesPC(Ph)(py)}Cl 2 ] which exhibited a substantially shortened PQC bond and catalytic activity in the Overman-Claisen rearrangement. 72 The SPS pincer complexes [Pd{PhP(C 6 H 4 -2-S) 2 }(PAr 3 )] [Ar = C 6 H 4 R-4, R = Cl, F, Me and CF 3 ] have been evaluated for activity in Heck coupling reactions, 73 whilst the structurally similar [Pd{PhP(C 6 H 4 -2-SCH 2 Cl)(C 6 H 4 -2-S)}(dppe)]Cl has proven to be an example of hemilability and dichloromethane activation.…”

Section: Coordination Chemistrymentioning

confidence: 99%

Nickel, palladium and platinum

Fletcher

2008

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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This chapter reviews the literature for 2007 on the chemistry of group 10 elements giving an overview of new preparative procedures and structural motifs of simple coordination and organometallic compounds. HighlightsOver the year a number of exciting developments have been made, attention is drawn to the permittivity measurements on a novel homochiral trinuclear nickel(II) complex which reveals a huge and stable dielectric temperature independent anisotropic effect, 1 a discrete triangular tripalladium arene sandwich complex 2 and the first platinum-alane bond.

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Section: Coordination Chemistrymentioning

confidence: 99%