2024
DOI: 10.1021/acs.inorgchem.4c03500
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(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

Yu-Hang Wang,
De-Xuan Jiang,
De-Xuan Liu
et al.

Abstract: Birefringent crystals, which can modulate and polarize light, play a vital role in the development of optical sensors and optoelectronic devices. Herein, we synthesized a new birefringent crystal [(C 10 N 2 H 10 )-(HI 2 O 6 )(HIO 3 )(IO 3 )] with large birefringence by integrating the large πconjugated 4,4′-bipyridine group with two types of iodates anions ([IO 3 ] − and [HI 2 O 6 ] − ) characterized by high polarizability anisotropy and strong stereochemically active lone pairs (SCALP).The crystal exhibits a … Show more

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