“…developed a novel protocol for Pd(0)−catalyzed oxidative carbonylation of non‐directed benzylic C(sp 3 )−H bond [5] . Although significant progress has been made on chelation‐induced benzylic C(sp 3 )−H bond functionalization, [6] non‐directed benzylic C(sp 3 )−H bond functionalization is still less explored and a few of them were pioneered by Hiyama, [7a] Li, [7b] Landais, [7c] Chen, [7d] Chirik, [7e] Lei, [7f] Pandey, [7g] Xing, [7h] White, [7i] Takemoto, [7j] Qing, [7k] Shi, [7l] Wu, [7m] Bolm [7n] and Yamaguchi [7o] for Heck‐type couplings with diverse electrophiles (Scheme 1).…”