CS Bonds via CH Functionalization

Abstract

TOC Graphic image Abstract The development of CS bonds‐making methodology is mainly explored by condensing metal thiolate with prefunctionalized organic substrates. However, the synthesis of CS bonds via CH functionalization reactions has a significant impact on organic chemistry. Herein, we have collected the literature based on various CS bond formation reactions via CH functionalizations. This article has been subdivided into four categories: (i) metal‐catalysis, (ii) metal‐free reagent, (iii) photoredox catalysis, and (iv) electrochemical‐based.