C–O–H fluid-melt-rock interaction in graphitic granulites and problems of quantifying carbon budget in the lower continental crust

Carvalho, Bruna B.; Bartoli, Omar; Cesare, Bernardo

doi:10.1016/j.chemgeo.2023.121503

Cited by 9 publications

(1 citation statement)

References 107 publications

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“…Our phase equilibrium modelling does not consider C-bearing species, mainly due to the uncertainties around CO 2 solubility in silicate melt (e.g. Carvalho et al, 2023). However, if carbonate alteration occurred prior to high-grade metamorphism, then the presence of carbonate should decrease water activity and increase the solidus temperature (Khitarov & Kadik, 1973) resulting in less melting and therefore greater retention of HPE in the source-an implication discussed further in the text.…”

Section: Model Limitationsmentioning

confidence: 99%

Redistribution of heat‐producing elements during melting of Archean crust

Kinney,

Kendrick,

Duguet

et al. 2023

Journal Metamorphic Geology

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Heat generated from the decay of K, Th, and U plays a fundamental role in the differentiation and stabilization of Earth's continental crust. This is particularly important in the construction of Archean cratons that form the nuclei of Earth's continents. The Kapuskasing uplift is a rare exposure of an Archean‐age crustal cross‐section that provides a snapshot of crustal melting, differentiation, and compositional stratification. We integrate field observations, whole‐rock compositions, thermodynamic equilibrium and accessory mineral modelling with heat production and latency time modelling to provide insights into the partitioning of heat‐producing elements between residue and melt during anatexis of metabasites as well as the resulting effects on metamorphic timescales and the production of tonalite–trondhjemite–granodiorite (TTG) suites. We model six metabasite compositions ranging from relatively fertile greenschist facies metabasites to melt‐depleted residual mafic (upper‐)amphibolites to granulites. Heat‐producing elements are modelled to be partitioned between melt and residue; the dominant minerals in the residue that host these elements are apatite, hornblende, K‐feldspar, and epidote. At 800–850°C epidote is no longer stable, and the melt fraction is predicted to contain roughly half of the heat production capacity for the system. Apatite and melt are expected to be the dominant repositories for Th and U during anatexis; zircon is predicted to be completely consumed by 850°C, whereas apatite persists to higher temperatures and allanite is expected only in minor modal abundances at high‐P, low‐T conditions. The partitioning of heat‐producing elements into relatively low‐density melt decreases the heat production of the residual system during anatexis. Due to their high density and affinity for U and Th, epidote and apatite retain heat production capacity in the residue during metabasite melting. Thermal latency modelling of metamorphism suggests that enriched metabasite compositions require 38–46 My to increase the temperature from ~650 to 850°C (solidus temperature to peak metamorphic temperature of the Kapuskasing uplift), whereas estimates are considerably shorter for depleted compositions (7–25 My). Four of the six samples modelled require 60–70 My to reach 1000°C from the solidus. Our modelling of heat‐producing element partitioning and predicted proportions of melt suggest that enriched basaltic compositions are the most reasonable source of TTG magmas and our heating time modelling indicates the mantle as an equal to dominant source of heat for metabasite anatexis compared with radiogenic heat production.

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Section: Model Limitationsmentioning

confidence: 99%

Redistribution of heat‐producing elements during melting of Archean crust

Kinney,

Kendrick,

Duguet

et al. 2023

Journal Metamorphic Geology

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High-pressure melting in metapelites of a 2 Ga old subducted oceanic crust (Usagaran belt, Tanzania): implications from melt inclusions, fluid inclusions and thermodynamic modelling

Herms,

Raase,

Giehl

et al. 2023

Contrib Mineral Petrol

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Investigation of polymineralic melt inclusions preserved in garnet of eclogite-facies metapelites of the Usagaran belt, Tanzania, is of particular importance as these metapelites, intercalated in oceanic metabasites, document the rare case of partial melting at high temperatures in a subducted oceanic crust. With an age of 2 Ga the rocks represent one of the oldest oceanic crusts and confirm a subduction process already at Paleoproterozoic times. Partial melting probably was initiated by dehydration melting under the presence of a CO2-rich fluid phase. The melt is preserved in siliceous polymineralic inclusions, while CO2 locally reacted with the garnet host to form dolomite-quartz-kyanite inclusions. During this reaction, the REE spectrum of garnet is adopted by the dolomite. Furthermore, graphite inclusions in garnet must have precipitated from the CO2 fluid by reduction. The highly ordered graphite structure indicates a formation temperature of at least 700 °C. Rehomogenization experiments of the siliceous polymineralic inclusions yield a homogeneous melt of rhyolitic, peraluminous composition. Thermodynamic modelling enables to deduce a P–T path in accordance with high P–T conditions (minimum 2.0 GPa, 900 °C) where a partial melt formed due to phengite breakdown leading to the preserved peak mineral assemblage garnet, alkali feldspar, kyanite, quartz and rutile. A very fast uplift of the oceanic crustal rocks can be deduced from the occurrence of very finely exsolved metastable ternary feldspar and from the preserved prograde zoning in garnet.

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Effectiveness of Ti-in-amphibole thermometry and performance of different thermometers across lower continental crust up to UHT metamorphism

Bartoli,

Carvalho,

Farina

2024

Contrib Mineral Petrol

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Metabasites are important constituents of deep crustal sections and are the favored rock type for studying lower crustal amphibolite to granulite transitions. However, metapelites may develop a larger number of temperature-sensitive mineral assemblages and are particular useful when extreme ultrahigh temperature (UHT) conditions are envisaged. A recent calibration of the Ti-in-amphibole thermometer by Liao et al. (2021) was supposed to make thermometry on metabasites quick and easy to apply. However, their calibration is based on experiments which were not originally designed to investigate in detail the temperature dependence of Ti in amphibole. In addition, a possible effect of aTiO2 and/or pressure on the Ti content of amphibole was not fully taken into account. This resulted in a calibration uncertainty of ± 70 °C (2σ), much higher than that of other single-mineral thermometers. In this study we firstly test the newly calibrated Ti-in-amphibole thermometer across the mid to lower crustal section of the Ivrea–Verbano Zone (IVZ; NW Italy) and compare the performance of different thermometric techniques across the sequence. Ti-in-amphibole thermometry records increasing peak temperatures from amphibolite (600–700 °C), transition (750–800 °C) and granulite (850–950 °C) zones. Titanium content of amphibole may be modified by retrograde fluid influx returning temperatures c. 200–300 °C lower than in non-altered domains. The comparison reveals that Zr-in-rutile thermometer in pelitic granulites seems to be more prone to post-peak resetting than the Ti-in-amphibole thermometry in nearby mafic rocks. This behavior is also confirmed by amphibole analyses from other UHT localities, where the performance of Ti-in-amphibole thermometry is comparable with that of Al-in-orthopyroxene in pelitic granulites. However, Ti-in-amphibole temperatures are underestimated in rutile-bearing samples and this limitation is not solely restricted to rocks containing high H2O contents as previously thought. Derived constraints on the diffusivity of Ti through amphibole demonstrate the robustness of the Ti-in-amphibole thermometer to later thermal disturbances. However, ad-hoc experiments are still necessary to improve the accuracy and precision of calibration and to extend its applicability. This advance will make mafic granulites routine targets for studies devoted to understanding the regional extent of UHT metamorphism.

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C–O–H fluid-melt-rock interaction in graphitic granulites and problems of quantifying carbon budget in the lower continental crust

Cited by 9 publications

References 107 publications

Redistribution of heat‐producing elements during melting of Archean crust

Redistribution of heat‐producing elements during melting of Archean crust

High-pressure melting in metapelites of a 2 Ga old subducted oceanic crust (Usagaran belt, Tanzania): implications from melt inclusions, fluid inclusions and thermodynamic modelling

Effectiveness of Ti-in-amphibole thermometry and performance of different thermometers across lower continental crust up to UHT metamorphism

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