[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

Zhang, Yang; Lv, Meng-Han; Li, Shu-Fang; Huang, Hongbo; Zhang, Bingbing; Yan, Dong

doi:10.1016/j.jssc.2024.124823

Journal of Solid State Chemistry

2024

DOI: 10.1016/j.jssc.2024.124823

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[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

Yang Zhang,

Meng-Han Lv,

Shu-Fang Li

et al.

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2024

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Cited by 3 publications

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Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Zhou,

Cheng,

Chu

et al. 2024

Angewandte Chemie

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Deep‐ultraviolet (UV) birefringent materials are urgently needed to facilitate light polarization in deep‐UV lithography. Maximizing anisotropy by regulating the alignment of functional modules is essential for improving the linear optical performance of birefringent materials. In this work, we proposed a strategy to design deep‐UV birefringent materials that achieve functional module ordering via weak interactions. Following this strategy, four compounds CN4H7SO3CF3, CN4H7SO3CH3, C(NH2)3SO3CH3, and C(NH2)3SO3CF3 were identified as high‐performance candidates for deep‐UV birefringent materials. The millimeter‐sized crystals of CN4H7SO3CF3, CN4H7SO3CH3, and C(NH2)3SO3CH3 were grown, and the transmittance spectra show that their cutoff edges are below 200 nm. CN4H7SO3CF3 exhibits the largest birefringence (0.149 @ 546 nm, 0.395 @ 200 nm) in the deep‐UV region among reported sulfates and sulfate derivatives. It reveals that the hydrogen bond can modulate the module ordering of the heteroleptic tetrahedra and planar π‐conjugated cations, thus greatly enhancing the birefringence. Our study not only discovers new deep‐UV birefringent materials but also provides an upgraded strategy for optimizing optical anisotropy to achieve efficient birefringence.

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Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Zhou,

Cheng,

Chu

et al. 2024

Angewandte Chemie

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Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Zhou,

Cheng,

Chu

et al. 2024

Angew Chem Int Ed

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Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

Jia,

Hou,

Pan

2024

Inorg. Chem. Front.

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[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

Cited by 3 publications

References 47 publications

Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

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