Abstract:A dye-sensitized betavoltaic cell is developed for the first time, which utilizes radioisotopic carbon, composed of nano-sized quantum dots, and ruthenium-based dye sensitized TiO2 as electrodes.
“…Though the cost of radioisotopes is high, it can be overcome through structural processes that can improve the emitted βradiation energy per unit area. 30 It is important to note that a betavoltaic battery is cost-effective in the long term due to its ability to operate for decades with minimum maintenance costs. 19 2.3. β-Radiation Absorbing Materials.…”
Section: Selection Of β-Radiationmentioning
confidence: 99%
“…The radioisotopes used in betavoltaic batteries are primarily obtained as byproducts of fission reactions in nuclear power plants or artificially produced using accelerators and/or neutron capture. Though the cost of radioisotopes is high, it can be overcome through structural processes that can improve the emitted β-radiation energy per unit area . It is important to note that a betavoltaic battery is cost-effective in the long term due to its ability to operate for decades with minimum maintenance costs …”
Section: Insight
Into Betavoltaic Batterymentioning
confidence: 99%
“…(d) Comparison of blank cell (no dye/no radiation), dye-sensitized cell (dye/no radiation), betavoltaic cell (pristine cell, no dye/radiation) (no dye/radiation) and dye-sensitized betavoltaic cell (dye/radiation) J–V characteristics (inset image is a nano/quantum radioisotope carbon dye-sensitized betavoltaic cell). (c) and (d) reproduced with permission from ref . Copyright 2020, The Royal Society of Chemistry (RSC).…”
Section: Materials For the Betavoltaic
Batteriesmentioning
confidence: 99%
“…The benefits of the metal complex molecules can be applied to betavoltaic battery as well. Hwang et al developed for the first time a dye-sensitized betavoltaic cell (DSBC) that utilized a radioisotope of carbon ( 14 C) as the source . The electrodes of the DSBC consisted of nanosized quantum dots containing the 14 C source and ruthenium-based dye-sensitized TiO 2 , as shown in Figure c.…”
Section: Materials For the Betavoltaic
Batteriesmentioning
confidence: 99%
“…Hwang et al developed for the first time a dye-sensitized betavoltaic cell (DSBC) that utilized a radioisotope of carbon ( 14 C) as the source. 30 The electrodes of the DSBC consisted of nanosized quantum dots containing the 14 C source and ruthenium-based dye-sensitized TiO 2 , as shown in Figure 10c. The energy provided by the β-radiation transferred the charge from the ruthenium metal ion to the ligand via a metal-to-ligand charge transition (MLCT).…”
Nuclear energy is considered a suitable and eco-friendly alternative for combating the rising greenhouse gases in the atmosphere from excessive fossil fuel consumption. Betavoltaic battery is a form of nuclear technology that utilizes the decay energy of β-emitting radioisotopes to produce electrical power. Owing to its long shelf life, high specific energy density, and ability to work under extreme conditions, it has been a subject of considerable research attention in the past few years. Despite significant research on betavoltaic battery, several impediments to realizing high energy conversion efficiency and maximum power density have yet to be overcome. This Review Article comprehensively discusses the challenges and recent research progress of betavoltaic battery development. First, promising strategies for improving betavoltaic battery performance, theoretical principles, and equations for quantifying betavoltaic battery efficiency are discussed. Then a thorough overview of several β-radiation absorbing materials, such as traditional semiconductors, metal oxides, and organic/inorganic materials, is explored. Finally, the outlook for betavoltaic battery is discussed before concluding the review.
“…Though the cost of radioisotopes is high, it can be overcome through structural processes that can improve the emitted βradiation energy per unit area. 30 It is important to note that a betavoltaic battery is cost-effective in the long term due to its ability to operate for decades with minimum maintenance costs. 19 2.3. β-Radiation Absorbing Materials.…”
Section: Selection Of β-Radiationmentioning
confidence: 99%
“…The radioisotopes used in betavoltaic batteries are primarily obtained as byproducts of fission reactions in nuclear power plants or artificially produced using accelerators and/or neutron capture. Though the cost of radioisotopes is high, it can be overcome through structural processes that can improve the emitted β-radiation energy per unit area . It is important to note that a betavoltaic battery is cost-effective in the long term due to its ability to operate for decades with minimum maintenance costs …”
Section: Insight
Into Betavoltaic Batterymentioning
confidence: 99%
“…(d) Comparison of blank cell (no dye/no radiation), dye-sensitized cell (dye/no radiation), betavoltaic cell (pristine cell, no dye/radiation) (no dye/radiation) and dye-sensitized betavoltaic cell (dye/radiation) J–V characteristics (inset image is a nano/quantum radioisotope carbon dye-sensitized betavoltaic cell). (c) and (d) reproduced with permission from ref . Copyright 2020, The Royal Society of Chemistry (RSC).…”
Section: Materials For the Betavoltaic
Batteriesmentioning
confidence: 99%
“…The benefits of the metal complex molecules can be applied to betavoltaic battery as well. Hwang et al developed for the first time a dye-sensitized betavoltaic cell (DSBC) that utilized a radioisotope of carbon ( 14 C) as the source . The electrodes of the DSBC consisted of nanosized quantum dots containing the 14 C source and ruthenium-based dye-sensitized TiO 2 , as shown in Figure c.…”
Section: Materials For the Betavoltaic
Batteriesmentioning
confidence: 99%
“…Hwang et al developed for the first time a dye-sensitized betavoltaic cell (DSBC) that utilized a radioisotope of carbon ( 14 C) as the source. 30 The electrodes of the DSBC consisted of nanosized quantum dots containing the 14 C source and ruthenium-based dye-sensitized TiO 2 , as shown in Figure 10c. The energy provided by the β-radiation transferred the charge from the ruthenium metal ion to the ligand via a metal-to-ligand charge transition (MLCT).…”
Nuclear energy is considered a suitable and eco-friendly alternative for combating the rising greenhouse gases in the atmosphere from excessive fossil fuel consumption. Betavoltaic battery is a form of nuclear technology that utilizes the decay energy of β-emitting radioisotopes to produce electrical power. Owing to its long shelf life, high specific energy density, and ability to work under extreme conditions, it has been a subject of considerable research attention in the past few years. Despite significant research on betavoltaic battery, several impediments to realizing high energy conversion efficiency and maximum power density have yet to be overcome. This Review Article comprehensively discusses the challenges and recent research progress of betavoltaic battery development. First, promising strategies for improving betavoltaic battery performance, theoretical principles, and equations for quantifying betavoltaic battery efficiency are discussed. Then a thorough overview of several β-radiation absorbing materials, such as traditional semiconductors, metal oxides, and organic/inorganic materials, is explored. Finally, the outlook for betavoltaic battery is discussed before concluding the review.
Non‐peripherally, glycerol terminal groups substituted copper (II) phthalocyanine were non‐covalently (electrostatic and/or π–π interaction) attached to carbon (CQD) and carbon‐boron quantum dots (CBQD) to form QDs‐Pc nanoconjugate systems. Synthesized novel phthalocyanine compounds and QDs‐Pc conjugate systems were characterized using different spectroscopic techniques. Various biological assessments were applied to newly synthesized compounds. Conjugates 4 and 5 had a maximal free radical scavenging activity of 71.3% and 68.1% at a 100 mg/L concentration. Compounds exhibited high antidiabetic activities at 200 mg/L. Also, compounds showed significant DNA nuclease activity at all tested concentrations. The most efficient MIC value was obtained as 4 mg/L against Enterococcus hirae and Enterococcus feacalis. This MIC value was further decreased after photodynamic therapy, and it was observed that the antimicrobial effects of the compounds increased. Inhibition of microbial cell viability was obtained as 100% for all compounds. In addition, compounds exerted perfect biofilm inhibitory effects.
We synthesized a pyrene‐based sensitive fluorescent chemosensor, TPA‐Cl ((E)‐N,N,N‐trimethyl‐2‐oxo‐2‐(2‐(pyren‐1‐ylmethylene)hydrazinyl)ethan‐1‐aminium chloride), to detect hypochlorite in a perfect aqueous solution. TPA‐Cl showed high selectivity for hypochlorite through fluorescence color change from sky blue to blue. The detection limit for hypochlorite was calculated as 0.27 μM, which is a quite low value. Moreover, the presence of other anions or ROS hardly hindered the sensing of hypochlorite by TPA‐Cl. Furthermore, TPA‐Cl could be applied successfully as a test kit for the simple recognition of hypochlorite. Surprisingly, TPA‐Cl is the first pyrene‐based fluorescent chemosensor that can detect ClO− by using the TPA‐Cl‐coated test kit. Moreover, TPA‐Cl could achieve the quantification of ClO− in various environmental water samples. The hydrolytic cleavage and oxidation mechanism of TPA‐Cl by hypochlorite was elucidated through UV–vis and fluorescent spectroscopy, 1H NMR titration, ESI‐MS analysis and DFT calculation.
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