By-Products of the Carbide Industry: The Manufacture of Ethylidene Diacetate and Vinyl Acetate

Morrison, George O.; Shaw, T.

doi:10.1149/1.3493831

Cited by 23 publications

(5 citation statements)

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“…Previously reported data include the solubility of C02 in n-tetracosane or n-dotrlacontane (1) and In naphthalene or biphenyl (2). Barrlck et al (3) reported the solubility of C02 In phenanthrene or pyrene at temperatures to 439.15 K. In the present study, the vapor-liquid equilibria of C02 In three-ring and four-ring aromatic solvents phenanthrene and pyrene have been measured at temperature ranges from 423.15 to 523.15 K and 473.15 to 573.15 K, respectively, and pressures from 10 to 50 atm. Henry constants, the partial molar volumes of C02 at Infinite dilution, and the Margules parameters are obtained by fitting the Krlchevsky-Illnskaya equation (4) to the solubility data.…”

Section: Introductionmentioning

confidence: 61%

“…The solubility of CO In mixed solvents Is characterized by a maximum for TCE + DMA and DMA + DBF systems and a minimum for the TCE + DBF system. The results could be well described by the expression In = xt In W, + x2 In W2 (3) which Is the usual type of equation valid for ideal systems (8). The percent error between estimated (right-hand side of eq 3) and experimental values of H for the mixture was always less than ±3%.…”

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confidence: 88%

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Vapor-liquid equilibria at 760 mmHg for the system vinyl acetate-n-decane

Escudero¹,

Martı́nez²,

Rodriguez³

1992

J. Chem. Eng. Data

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Section: Introductionmentioning

confidence: 61%

mentioning

confidence: 88%

Vapor-liquid equilibria at 760 mmHg for the system vinyl acetate-n-decane

Escudero¹,

Martı́nez²,

Rodriguez³

1992

J. Chem. Eng. Data

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“…8. "Calculated from the solubility (40) and vapor pressure (41). "Calculated from the solubility (29) and vapor pressure (27 model with a verv limited number of Darameters.…”

Section: Discussionmentioning

confidence: 99%

Concerning the distant polar interaction in free energies of transfer. An explanation and an estimation procedure

Guthrie¹

1991

Can. J. Chem.

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For polyfunctional compounds, free energies of transfer from gas to aqueous solution require corrections for the interactions of polar groups (Distant Polar Interactions). These corrections can be made with very few adjustable parameters by using a model of the solvation process assuming hydrogen bonding is the major source of the effect on free energy of transfer for polar groups, and that hydrogen bonding is perturbed by polar effects, measured by Taft o*. Parameters evaluated for polyfluoro, polychloro, and polybromo compounds successfully predicted the free energies of transfer for mixed polyhalogen compounds. Preliminary parameters have been evaluated for ethers, amines, phenyl groups, nitriles, and esters.

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“…This rate of hydrolysis of vinyl acetate is 1000 times that of its saturated analogue, ethyl acetate, in alkaline media (15). The rate of hydrolysis is minimal at pH 4.44 (16). Other 92 60 chemical reactions which vinyl acetate may undergo are addition across the double bond, transesterification to other vinyl esters, and oxidation (15,16,17,18,19,20,21).…”

Section: Introductionmentioning

confidence: 99%

Vinyl Acetate Polymers

Cordeiro¹,

Petrocelli²

2005

Kirk-Othmer Encyclopedia of Chemical Technology

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This article provides information related to the chemistry, manufacture, and use of poly(vinyl acetate). Summary information is provided on vinyl acetate as the primary ingredient in the manufacture of the polymer. This information focuses on the chemical and physical properties of the material and the handling and safety aspects pertinent to its use in a polymerization system. The key material properties of poly(vinyl acetate) homopolymer and copolymers are described. The influences of key components of the polymerization recipe are discussed, such as the effect of the stabilizers, comonomers, and chain‐transfer agents on the reaction and product. Polymerization process aspects are covered with a focus on emulsion polymerization. The mechanisms involved in the vinyl acetate polymerization reaction are discussed. An overview is provided of the applications of the homopolymer and copolymers in adhesives, paint, paper, and other areas. General information is provided in these areas with references which can be used to obtain more specific information.

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By-Products of the Carbide Industry: The Manufacture of Ethylidene Diacetate and Vinyl Acetate

Cited by 23 publications

References 0 publications

Vapor-liquid equilibria at 760 mmHg for the system vinyl acetate-n-decane

Vapor-liquid equilibria at 760 mmHg for the system vinyl acetate-n-decane

Concerning the distant polar interaction in free energies of transfer. An explanation and an estimation procedure

Vinyl Acetate Polymers

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