Bulk Crystal Growth and Optical and Thermal Properties of the Nonlinear Optical Crystal <scp>l</scp>-Histidinium-4-nitrophenolate 4-Nitrophenol (LHPP)

Chen, Tianliang; Sun, Zhihua; Cheng, Song; Yan, Gao; Lin, Wenxiong; Hong, Maochun

doi:10.1021/cg300262t

Cited by 59 publications

(21 citation statements)

References 30 publications

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“…For multiple-shot regime measurements 100 pulses were used (10 sec of laser radiation with 10 Hz pulse rate). If to compare measured LIDT values of herein studied co-crystals with some organic crystals and co-crystals (Table 3), one can see that LHPP crystal 38 consists same 4-nitrophenol-4nitrophenolate motif and exhibits almost the same LIDT value for single shot regime. 2AP4N crystal show best results for SHG (up to 10 times more than Urea crystal 36 ) but has twice less LIDT value than that of Urea.…”

Section: Resultsmentioning

confidence: 88%

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Organic noncentrosymmetric complexes of 4-nitrophenol for second harmonic generation

Pavlovetc

Draguta

Fokina

et al. 2015

Pacific Rim Laser Damage 2015: Optical Materials for High-Power Lasers

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The paper reports synthesis and co-crystallization of 5 co-crystal of 4-nitrophenol (4N) with five different monoand diaminopyridines (4-aminopyridine (4AP); 3,4-diaminopyridine (34DAP); 2-amino-6-methylpyridine (26MAP); 2,6-diaminopyridine (26DAP); 2-aminopyridine (2AP)) resulted in five adducts with the molar ratio of components 2:1 in final compounds. X-ray analysis confirms the non-centrosymmetric packing of obtained compounds. Two compounds crystallize in the polar acentric P21 and three compounds crystallize in acentric orthorhombic Pna21 space groups. The comparative studies on the laser induced multiple and single shot damage thresholds of named crystals were carried out using radiation of 1064 nm from Nd:YAG laser with pulse width 10 ns. Obtained results show good laser-induced singleshot and multiple-shot damage threshold values for all studied co-crystals and are found up to 3.64 GW/cm 2 and 1.77 GW/cm 2 respectively.

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Section: Resultsmentioning

confidence: 88%

“…Several groups of scientists performed measurements with similar scheme and calculations [37][38][39][40][41] . The obtained experimental laser induced damage threshold data for studied crystals is shown in Table 3.…”

Section: Resultsmentioning

confidence: 99%

Organic noncentrosymmetric complexes of 4-nitrophenol for second harmonic generation

Pavlovetc

Draguta

Fokina

et al. 2015

Pacific Rim Laser Damage 2015: Optical Materials for High-Power Lasers

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“…For LLNP crystal, the cut‐off wavelength occurs at 480 nm due to the electronic transitions in pNP, which is similar to sodium p‐nitrophenolate dehydrate and LAPP, etc. . The absorption peaks of benzene are mainly around 200 nm, while the hydroxyl and nitro groups of pNP lead to red shift of the absorption .…”

Section: Resultsmentioning

confidence: 94%

“…Therefore, some pNP derivative crystals with high NLO coefficient have been investigated, such as L‐arginine p‐nitrophenolate monohydrate, L‐arginine p‐nitrophenolate p‐nitrophenol dehydrate and L‐histidinium p‐nitrophenolate p‐nitrophenol, etc. . However, no research has been reported on the combination of the Llys and pNP to obtain new NLO materials.…”

Section: Introductionmentioning

confidence: 99%

Crystal growth, structure and spectroscopic studies of a novel organic single crystal: L‐lysine p‐nitrophenolate monohydrate (LLNP)

Wang

Zhang

Liu

et al. 2013

Crystal Research and Technology

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A novel organic crystal, L-lysine p-nitrophenolate monohydrate (LLNP) has been grown successfully from an aqueous solution by the slow cooling method. Transparent single crystal of dimensions 22 × 12 × 12 mm 3 has been obtained. The single crystal X-ray diffraction has shown that LLNP belongs to the orthorhombic crystallographic system with space group P2 1 2 1 2 1 . The functional groups and vibrational frequencies of the crystal have been identified using IR and Raman spectra. The proton and carbon configurations have been confirmed through 1 H-NMR and 13 C-NMR spectra analyses. The UV-Vis-NIR transmittance spectrum for LLNP crystal has been recorded in the range from 200 to 2500 nm. The second harmonic generation (SHG) intensity of LLNP has been measured by powder SHG method and found to be as 4.2 times as that of KDP. The thermal properties have been studied by using thermo gravimetric (TG) and differential thermal analysis (DTA).

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“…These strategies have generated many noncentrosymmetric and/or chiral organic crystals. [11][12][13][14][15] On the other hand, dyes with strong absorption in the near-infrared (NIR) region of electromagnetic radiation (approximately 750-3000 nm) are presently finding widespread applications in diverse fields such as the conversion of solar energy to electrical energy, optical communications, bioimaging, biosensors, thermal therapy and optoelectronics. [16][17][18][19][20][21] NIR organic materials can potentially be used in NIR devices, due to their low cost, light weight and flexibility.…”

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confidence: 99%

Phosphorescence, near-infrared absorption and nonlinear optical property of a new chiral organic crystal

Zhang

Zhao

Yong

2014

Funct. Mater. Lett.

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A new enantiomerically pure compound was synthesized by the single step reduced reaction from 2-(imidazo[1,2-a]pyridin-2-yl)-2-oxo-N-(pyridin-2-yl)acetamide via chiral induction with D-tartaric acid in good yield. Single crystal data confirm this compound crystallizes in chiral space group P2 1 . Transmission spectrum reveals that the crystal has low UV cut-off of 372 nm and has a good transmittance in the entire visible and near-infrared (NIR)region to 1100 nm, indicating its optical application. Kurtz powder test shows a good second harmonic generation (SHG) which also demonstrates its chiral structure. Moreover, this material exhibits blue phosphorescence with quantum yield of 3.6% and unusually NIR absorption between 1500 nm and 2500 nm. Therefore, this new chiral crystal is a promising multifunctional material for the blue phosphorescence, NIR absorption and nonlinear optical (NLO) applications.Organic noncentrosymmetric materials which probably have nonlinear optical (NLO) properties have received considerable attention due to their potential applications in frequency conversion, optical limiting, electro-optic modulation and in the investigation of nonlocal effects. Such materials offer numerous design possibilities and larger and faster optical nonlinearities when compared to their inorganic counterparts. 1,2 The strong macroscopic second-order nonlinearity requires a noncentrosymmetric crystal structure. Unfortunately, only a few molecules crystallize in noncentrosymmetric style, and even fewer of them are useful for NLO materials. Many approaches have been developed to produce noncentrosymmetric structure, e.g. designing molecules with small ground-state dipole moments, 3 choosing pure enantiomers, 4-7 halogen hydrogen bonding, 8,9 meta-substitution 10 and so on. These strategies have generated many noncentrosymmetric and/or chiral organic crystals. [11][12][13][14][15] On the other hand, dyes with strong absorption in the near-infrared (NIR) region of electromagnetic radiation (approximately 750-3000 nm) are presently finding widespread applications in diverse fields such as the conversion of solar energy to electrical energy, optical communications, bioimaging, biosensors, thermal therapy and optoelectronics. 16-21 NIR organic materials can potentially be used in NIR devices, due to their low cost, light weight and flexibility. However, commercially available NIR organic materials with absorption in the range of 1000-2000 nm are extremely rare. 20,22 Moreover, many organic compounds with conjugated bond systems are known to be deeply colored and act as NIR absorbers. [23][24][25][26][27] To date, purely organic luminogenic molecules that are also phosphorescent are very rare, 28 because the highly bonded nature of electrons in metal-free organic molecules makes them little freedom and less impetus to emit from triplet states. Phosphorescence is therefore generally regarded as a solely inorganic or organometallic property. Although most purely organic materials have been considered to be nonphosphoresc...

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Bulk Crystal Growth and Optical and Thermal Properties of the Nonlinear Optical Crystal l-Histidinium-4-nitrophenolate 4-Nitrophenol (LHPP)

Cited by 59 publications

References 30 publications

Organic noncentrosymmetric complexes of 4-nitrophenol for second harmonic generation

Organic noncentrosymmetric complexes of 4-nitrophenol for second harmonic generation

Crystal growth, structure and spectroscopic studies of a novel organic single crystal: L‐lysine p‐nitrophenolate monohydrate (LLNP)

Phosphorescence, near-infrared absorption and nonlinear optical property of a new chiral organic crystal

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